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catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water molecules and two 1,4-bis(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octahedral geometry. The 1,4-bis(1,2,4-triazol-yl)butane l...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011647/ https://www.ncbi.nlm.nih.gov/pubmed/21589229 http://dx.doi.org/10.1107/S1600536810045009 |
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author | Song, Jing-Jing Zhang, Kou-Lin Ng, Seik Weng |
author_facet | Song, Jing-Jing Zhang, Kou-Lin Ng, Seik Weng |
author_sort | Song, Jing-Jing |
collection | PubMed |
description | In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water molecules and two 1,4-bis(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octahedral geometry. The 1,4-bis(1,2,4-triazol-yl)butane ligand is centrosymmetric, the mid-point of the central C—C bond being located on an inversion center. It links adjacent water-coordinated metal atoms into polymeric chains running along the c axis. Adjacent chains are linked by O—H⋯N hydrogen bonds. The S atom of the sulfate anion is located on a twofold rotation axis, thus the sulfate anion is equally disordered over two sites. The sulfate anion links with the polymeric chains via O—H⋯O hydrogen bonds, generating a three-dimensional supramolecular network. |
format | Text |
id | pubmed-3011647 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116472010-12-30 catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate] Song, Jing-Jing Zhang, Kou-Lin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water molecules and two 1,4-bis(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octahedral geometry. The 1,4-bis(1,2,4-triazol-yl)butane ligand is centrosymmetric, the mid-point of the central C—C bond being located on an inversion center. It links adjacent water-coordinated metal atoms into polymeric chains running along the c axis. Adjacent chains are linked by O—H⋯N hydrogen bonds. The S atom of the sulfate anion is located on a twofold rotation axis, thus the sulfate anion is equally disordered over two sites. The sulfate anion links with the polymeric chains via O—H⋯O hydrogen bonds, generating a three-dimensional supramolecular network. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011647/ /pubmed/21589229 http://dx.doi.org/10.1107/S1600536810045009 Text en © Song et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Jing-Jing Zhang, Kou-Lin Ng, Seik Weng catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate] |
title |
catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N
(4):N
(4′)]cadmium(II)] sulfate] |
title_full |
catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N
(4):N
(4′)]cadmium(II)] sulfate] |
title_fullStr |
catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N
(4):N
(4′)]cadmium(II)] sulfate] |
title_full_unstemmed |
catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N
(4):N
(4′)]cadmium(II)] sulfate] |
title_short |
catena-Poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
N
(4):N
(4′)]cadmium(II)] sulfate] |
title_sort | catena-poly[[tetraaqua[μ(2)-1,4-bis(1,2,4-triazol-1-yl)butane-κ(2)
n
(4):n
(4′)]cadmium(ii)] sulfate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011647/ https://www.ncbi.nlm.nih.gov/pubmed/21589229 http://dx.doi.org/10.1107/S1600536810045009 |
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