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catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]

In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water mol­ecules and two 1,4-bis­(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octa­hedral geometry. The 1,4-bis­(1,2,4-triazol-yl)butane l...

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Detalles Bibliográficos
Autores principales: Song, Jing-Jing, Zhang, Kou-Lin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011647/
https://www.ncbi.nlm.nih.gov/pubmed/21589229
http://dx.doi.org/10.1107/S1600536810045009
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author Song, Jing-Jing
Zhang, Kou-Lin
Ng, Seik Weng
author_facet Song, Jing-Jing
Zhang, Kou-Lin
Ng, Seik Weng
author_sort Song, Jing-Jing
collection PubMed
description In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water mol­ecules and two 1,4-bis­(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octa­hedral geometry. The 1,4-bis­(1,2,4-triazol-yl)butane ligand is centrosymmetric, the mid-point of the central C—C bond being located on an inversion center. It links adjacent water-coordinated metal atoms into polymeric chains running along the c axis. Adjacent chains are linked by O—H⋯N hydrogen bonds. The S atom of the sulfate anion is located on a twofold rotation axis, thus the sulfate anion is equally disordered over two sites. The sulfate anion links with the polymeric chains via O—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular network.
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spelling pubmed-30116472010-12-30 catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate] Song, Jing-Jing Zhang, Kou-Lin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, {[Cd(C(8)H(12)N(6))(H(2)O)(4)]SO(4)}(n), the Cd(II) atom is located on an inversion center and coordinated by four water mol­ecules and two 1,4-bis­(1,2,4-triazol-yl)butane ligands in a distorted CdO(4)N(2) octa­hedral geometry. The 1,4-bis­(1,2,4-triazol-yl)butane ligand is centrosymmetric, the mid-point of the central C—C bond being located on an inversion center. It links adjacent water-coordinated metal atoms into polymeric chains running along the c axis. Adjacent chains are linked by O—H⋯N hydrogen bonds. The S atom of the sulfate anion is located on a twofold rotation axis, thus the sulfate anion is equally disordered over two sites. The sulfate anion links with the polymeric chains via O—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular network. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011647/ /pubmed/21589229 http://dx.doi.org/10.1107/S1600536810045009 Text en © Song et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Jing-Jing
Zhang, Kou-Lin
Ng, Seik Weng
catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title_full catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title_fullStr catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title_full_unstemmed catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title_short catena-Poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)]cadmium(II)] sulfate]
title_sort catena-poly[[tetra­aqua­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) n (4):n (4′)]cadmium(ii)] sulfate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011647/
https://www.ncbi.nlm.nih.gov/pubmed/21589229
http://dx.doi.org/10.1107/S1600536810045009
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