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Bis(2-aminopyridinium) tetra­chloridozincate(II)

In the title compound, (C(5)H(7)N(2))(2)[ZnCl(4)], the pyridine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, weak N—H⋯Cl hydrogen bonds link the mol­ecules into layers, while weak π–π inter­actions [centroid–centroid dista...

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Detalles Bibliográficos
Autores principales: Cai, Hong-ling, Fu, Xue-qun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011649/
https://www.ncbi.nlm.nih.gov/pubmed/21589278
http://dx.doi.org/10.1107/S1600536810046817
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author Cai, Hong-ling
Fu, Xue-qun
author_facet Cai, Hong-ling
Fu, Xue-qun
author_sort Cai, Hong-ling
collection PubMed
description In the title compound, (C(5)H(7)N(2))(2)[ZnCl(4)], the pyridine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, weak N—H⋯Cl hydrogen bonds link the mol­ecules into layers, while weak π–π inter­actions [centroid–centroid distance = 4.2758 (18) Å] also help to stabilize the packing.
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spelling pubmed-30116492010-12-30 Bis(2-aminopyridinium) tetra­chloridozincate(II) Cai, Hong-ling Fu, Xue-qun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(7)N(2))(2)[ZnCl(4)], the pyridine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, weak N—H⋯Cl hydrogen bonds link the mol­ecules into layers, while weak π–π inter­actions [centroid–centroid distance = 4.2758 (18) Å] also help to stabilize the packing. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011649/ /pubmed/21589278 http://dx.doi.org/10.1107/S1600536810046817 Text en © Cai and Fu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hong-ling
Fu, Xue-qun
Bis(2-aminopyridinium) tetra­chloridozincate(II)
title Bis(2-aminopyridinium) tetra­chloridozincate(II)
title_full Bis(2-aminopyridinium) tetra­chloridozincate(II)
title_fullStr Bis(2-aminopyridinium) tetra­chloridozincate(II)
title_full_unstemmed Bis(2-aminopyridinium) tetra­chloridozincate(II)
title_short Bis(2-aminopyridinium) tetra­chloridozincate(II)
title_sort bis(2-aminopyridinium) tetra­chloridozincate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011649/
https://www.ncbi.nlm.nih.gov/pubmed/21589278
http://dx.doi.org/10.1107/S1600536810046817
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AT fuxuequn bis2aminopyridiniumtetrachloridozincateii