Cargando…

2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate

In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intra­molecular O—H⋯N hydrogen bonds between the hy...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011653/
https://www.ncbi.nlm.nih.gov/pubmed/21589513
http://dx.doi.org/10.1107/S1600536810047185
_version_ 1782194994152472576
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intra­molecular O—H⋯N hydrogen bonds between the hy­droxy O atoms and the imine N atoms, with O⋯N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds occur and several intra- and inter­molecular π–π inter­actions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å.
format Text
id pubmed-3011653
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116532010-12-30 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intra­molecular O—H⋯N hydrogen bonds between the hy­droxy O atoms and the imine N atoms, with O⋯N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds occur and several intra- and inter­molecular π–π inter­actions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011653/ /pubmed/21589513 http://dx.doi.org/10.1107/S1600536810047185 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title_full 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title_fullStr 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title_full_unstemmed 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title_short 2-[(2-{Bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
title_sort 2-[(2-{bis[2-(2-hy­droxy-5-nitro­benzyl­idene­amino)­eth­yl]amino}­eth­yl)imino­meth­yl]-4-nitro­phenol acetonitrile monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011653/
https://www.ncbi.nlm.nih.gov/pubmed/21589513
http://dx.doi.org/10.1107/S1600536810047185
work_keys_str_mv AT hakwang 22bis22hydroxy5nitrobenzylideneaminoethylaminoethyliminomethyl4nitrophenolacetonitrilemonosolvate