Cargando…
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate
In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intramolecular O—H⋯N hydrogen bonds between the hy...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011653/ https://www.ncbi.nlm.nih.gov/pubmed/21589513 http://dx.doi.org/10.1107/S1600536810047185 |
_version_ | 1782194994152472576 |
---|---|
author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intramolecular O—H⋯N hydrogen bonds between the hydroxy O atoms and the imine N atoms, with O⋯N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds occur and several intra- and intermolecular π–π interactions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å. |
format | Text |
id | pubmed-3011653 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116532010-12-30 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(27)N(7)O(9)·CH(3)CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intramolecular O—H⋯N hydrogen bonds between the hydroxy O atoms and the imine N atoms, with O⋯N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds occur and several intra- and intermolecular π–π interactions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011653/ /pubmed/21589513 http://dx.doi.org/10.1107/S1600536810047185 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ha, Kwang 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title | 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_full | 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_fullStr | 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_full_unstemmed | 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_short | 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_sort | 2-[(2-{bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011653/ https://www.ncbi.nlm.nih.gov/pubmed/21589513 http://dx.doi.org/10.1107/S1600536810047185 |
work_keys_str_mv | AT hakwang 22bis22hydroxy5nitrobenzylideneaminoethylaminoethyliminomethyl4nitrophenolacetonitrilemonosolvate |