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1-Adamantylmethyl 2-amino­benzoate

The asymmetric unit of the title compound, C(18)H(23)NO(2), consists of two crystallographically independent mol­ecules bearing an adamantane cage consisting of three fused cyclo­hexane rings in almost ideal chair conformations, with C—C—C angles in the range 108.47 (16)–110.59 (15)°. Both aryl ring...

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Detalles Bibliográficos
Autores principales: Kozubková, Zuzana, Rouchal, Michal, Nečas, Marek, Vícha, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011654/
https://www.ncbi.nlm.nih.gov/pubmed/21589546
http://dx.doi.org/10.1107/S1600536810047276
Descripción
Sumario:The asymmetric unit of the title compound, C(18)H(23)NO(2), consists of two crystallographically independent mol­ecules bearing an adamantane cage consisting of three fused cyclo­hexane rings in almost ideal chair conformations, with C—C—C angles in the range 108.47 (16)–110.59 (15)°. Both aryl rings are essentially planar, the maximum deviation from the best plane being 0.0125 (19) Å. One conformer forms chains parallel to the b axis via N—H⋯O hydrogen bonds, whereas the second exhibits only an intra­molecular N—H⋯O hydrogen bond. The crystal structure is stabilized by further weak N—H⋯O and N—H⋯N inter­actions.