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Bis(μ-2,2′-disulfanediyldibenzoato)bis[aqua(2,2′-bipyridine)nickel(II)]
In the centrosymmetric title complex, [Ni(2)(C(14)H(8)O(4)S(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Ni(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxylate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011661/ https://www.ncbi.nlm.nih.gov/pubmed/21589252 http://dx.doi.org/10.1107/S1600536810045824 |
Sumario: | In the centrosymmetric title complex, [Ni(2)(C(14)H(8)O(4)S(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Ni(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxylate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O atom from a coordinated water molecule in an octahedral coordination geometry. The disulfanediyldibenzoate dianion bridges two Ni(II )atoms. Adjacent molecules are linked through the coordinated water molecules, forming a O—H⋯O hydrogen-bonded chain running along the a axis. |
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