Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]

In the centrosymmetric title complex, [Ni(2)(C(14)H(8)O(4)S(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Ni(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxyl­ate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Zhengming, Qu, Botao, Yu, Jianghua, Yuan, Limin, Liu, Wenlong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011661/
https://www.ncbi.nlm.nih.gov/pubmed/21589252
http://dx.doi.org/10.1107/S1600536810045824
_version_ 1782194996064026624
author Liu, Zhengming
Qu, Botao
Yu, Jianghua
Yuan, Limin
Liu, Wenlong
author_facet Liu, Zhengming
Qu, Botao
Yu, Jianghua
Yuan, Limin
Liu, Wenlong
author_sort Liu, Zhengming
collection PubMed
description In the centrosymmetric title complex, [Ni(2)(C(14)H(8)O(4)S(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Ni(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxyl­ate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O atom from a coordinated water mol­ecule in an octa­hedral coordination geometry. The disulfanediyldibenzo­ate dianion bridges two Ni(II )atoms. Adjacent mol­ecules are linked through the coordinated water mol­ecules, forming a O—H⋯O hydrogen-bonded chain running along the a axis.
format Text
id pubmed-3011661
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116612010-12-30 Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)] Liu, Zhengming Qu, Botao Yu, Jianghua Yuan, Limin Liu, Wenlong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Ni(2)(C(14)H(8)O(4)S(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Ni(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxyl­ate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O atom from a coordinated water mol­ecule in an octa­hedral coordination geometry. The disulfanediyldibenzo­ate dianion bridges two Ni(II )atoms. Adjacent mol­ecules are linked through the coordinated water mol­ecules, forming a O—H⋯O hydrogen-bonded chain running along the a axis. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011661/ /pubmed/21589252 http://dx.doi.org/10.1107/S1600536810045824 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Zhengming
Qu, Botao
Yu, Jianghua
Yuan, Limin
Liu, Wenlong
Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title_full Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title_fullStr Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title_full_unstemmed Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title_short Bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(II)]
title_sort bis(μ-2,2′-disulfanediyldibenzoato)bis­[aqua­(2,2′-bipyridine)­nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011661/
https://www.ncbi.nlm.nih.gov/pubmed/21589252
http://dx.doi.org/10.1107/S1600536810045824
work_keys_str_mv AT liuzhengming bism22disulfanediyldibenzoatobisaqua22bipyridinenickelii
AT qubotao bism22disulfanediyldibenzoatobisaqua22bipyridinenickelii
AT yujianghua bism22disulfanediyldibenzoatobisaqua22bipyridinenickelii
AT yuanlimin bism22disulfanediyldibenzoatobisaqua22bipyridinenickelii
AT liuwenlong bism22disulfanediyldibenzoatobisaqua22bipyridinenickelii

Ejemplares similares