1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate

The pyrrolidine-2,5-dione ring in the title compound, C(15)H(15)NO(6), is in a twisted conformation with the acetyl C atoms projecting to opposite sides of the ring. The acetyl groups lie to opposite sides of the five-membered ring. The benzene ring is roughly perpendicular to the heterocyclic ring,...

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Detalles Bibliográficos
Autores principales: Caracelli, Ignez, Ferreira, Fernando P., Vieira, Adriano S., Stefani, Hélio A., De Simone, Carlos A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011662/
https://www.ncbi.nlm.nih.gov/pubmed/21589357
http://dx.doi.org/10.1107/S1600536810043187
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author Caracelli, Ignez
Ferreira, Fernando P.
Vieira, Adriano S.
Stefani, Hélio A.
De Simone, Carlos A.
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Ferreira, Fernando P.
Vieira, Adriano S.
Stefani, Hélio A.
De Simone, Carlos A.
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The pyrrolidine-2,5-dione ring in the title compound, C(15)H(15)NO(6), is in a twisted conformation with the acetyl C atoms projecting to opposite sides of the ring. The acetyl groups lie to opposite sides of the five-membered ring. The benzene ring is roughly perpendicular to the heterocyclic ring, forming a dihedral angle of 76.57 (14)° with it. In the crystal, mol­ecules are connected through a network of C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-30116622010-12-30 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate Caracelli, Ignez Ferreira, Fernando P. Vieira, Adriano S. Stefani, Hélio A. De Simone, Carlos A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The pyrrolidine-2,5-dione ring in the title compound, C(15)H(15)NO(6), is in a twisted conformation with the acetyl C atoms projecting to opposite sides of the ring. The acetyl groups lie to opposite sides of the five-membered ring. The benzene ring is roughly perpendicular to the heterocyclic ring, forming a dihedral angle of 76.57 (14)° with it. In the crystal, mol­ecules are connected through a network of C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011662/ /pubmed/21589357 http://dx.doi.org/10.1107/S1600536810043187 Text en © Caracelli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Ferreira, Fernando P.
Vieira, Adriano S.
Stefani, Hélio A.
De Simone, Carlos A.
Tiekink, Edward R. T.
1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title_full 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title_fullStr 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title_full_unstemmed 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title_short 1-Benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
title_sort 1-benzyl-2,5-dioxopyrrolidine-3,4-diyl diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011662/
https://www.ncbi.nlm.nih.gov/pubmed/21589357
http://dx.doi.org/10.1107/S1600536810043187
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