{2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]

In the title compound, [Cu(C(15)H(26)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the catalytic asymmetric Gosteli–Claisen rearrangement, the central Cu(II) atom is in a nearly square-planar cis-N(2)O(2) environment in the cation arising from its coordination by an N,N-bide...

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Detalles Bibliográficos
Autores principales: Zeh, Julia, Möller, Melina, Strohmann, Carsten, Preut, Hans, Hiersemann, Martin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011664/
https://www.ncbi.nlm.nih.gov/pubmed/21589344
http://dx.doi.org/10.1107/S1600536810048658
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author Zeh, Julia
Möller, Melina
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
author_facet Zeh, Julia
Möller, Melina
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
author_sort Zeh, Julia
collection PubMed
description In the title compound, [Cu(C(15)H(26)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the catalytic asymmetric Gosteli–Claisen rearrangement, the central Cu(II) atom is in a nearly square-planar cis-N(2)O(2) environment in the cation arising from its coordination by an N,N-bidentate 2,2-bis­[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane ligand and two O-bonded N,N-dimethyl­formamide mol­ecules. Two SbF(6) (−) anions are positioned on opposite sides of the plane through the CuN(2)O(2) unit, generating an axially distorted CuN(2)O(2)F(2) octa­hedral geometry for the metal ion.
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spelling pubmed-30116642010-12-30 {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)] Zeh, Julia Möller, Melina Strohmann, Carsten Preut, Hans Hiersemann, Martin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(15)H(26)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the catalytic asymmetric Gosteli–Claisen rearrangement, the central Cu(II) atom is in a nearly square-planar cis-N(2)O(2) environment in the cation arising from its coordination by an N,N-bidentate 2,2-bis­[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane ligand and two O-bonded N,N-dimethyl­formamide mol­ecules. Two SbF(6) (−) anions are positioned on opposite sides of the plane through the CuN(2)O(2) unit, generating an axially distorted CuN(2)O(2)F(2) octa­hedral geometry for the metal ion. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011664/ /pubmed/21589344 http://dx.doi.org/10.1107/S1600536810048658 Text en © Zeh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeh, Julia
Möller, Melina
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
{2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title_full {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title_fullStr {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title_full_unstemmed {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title_short {2,2-Bis[(4S)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(N,N-dimethyl­formamide)­copper(II) bis­[hexa­fluoridoanti­monate(V)]
title_sort {2,2-bis[(4s)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]propane}­bis­(n,n-dimethyl­formamide)­copper(ii) bis­[hexa­fluoridoanti­monate(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011664/
https://www.ncbi.nlm.nih.gov/pubmed/21589344
http://dx.doi.org/10.1107/S1600536810048658
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