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(η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate
The title compound, [Ru(C(10)H(15))(C(10)H(12)O)][B(C(6)H(5))(4)], crystallizes as discrete (η(5)-pentamethylcyclopentadienyl)Ru(η(6)-4-phenylbutan-2-one)](+) cations and [BPh(4)](−) anions. In the cation, the non-H atoms of the butan-2-one group are approximately planar (r.m.s. deviation = 0....
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011665/ https://www.ncbi.nlm.nih.gov/pubmed/21589253 http://dx.doi.org/10.1107/S1600536810046064 |
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| author | Loughrey, Bradley T. Williams, Michael L. Healy, Peter C. |
| author_facet | Loughrey, Bradley T. Williams, Michael L. Healy, Peter C. |
| author_sort | Loughrey, Bradley T. |
| collection | PubMed |
| description | The title compound, [Ru(C(10)H(15))(C(10)H(12)O)][B(C(6)H(5))(4)], crystallizes as discrete (η(5)-pentamethylcyclopentadienyl)Ru(η(6)-4-phenylbutan-2-one)](+) cations and [BPh(4)](−) anions. In the cation, the non-H atoms of the butan-2-one group are approximately planar (r.m.s. deviation = 0.056 Å) and lie nearly perpendicular to the plane of the phenyl ring with a dihedral angle between the two planes of 69.3 (1)°. No significant C—H⋯O interactions are observed between the methyl and phenyl H atoms and the carbonyl O atom. |
| format | Text |
| id | pubmed-3011665 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30116652010-12-30 (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate Loughrey, Bradley T. Williams, Michael L. Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(10)H(15))(C(10)H(12)O)][B(C(6)H(5))(4)], crystallizes as discrete (η(5)-pentamethylcyclopentadienyl)Ru(η(6)-4-phenylbutan-2-one)](+) cations and [BPh(4)](−) anions. In the cation, the non-H atoms of the butan-2-one group are approximately planar (r.m.s. deviation = 0.056 Å) and lie nearly perpendicular to the plane of the phenyl ring with a dihedral angle between the two planes of 69.3 (1)°. No significant C—H⋯O interactions are observed between the methyl and phenyl H atoms and the carbonyl O atom. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011665/ /pubmed/21589253 http://dx.doi.org/10.1107/S1600536810046064 Text en © Loughrey et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Loughrey, Bradley T. Williams, Michael L. Healy, Peter C. (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title | (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title_full | (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title_fullStr | (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title_full_unstemmed | (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title_short | (η(5)-Pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate |
| title_sort | (η(5)-pentamethylcyclopentadienyl)(η(6)-4-phenylbutan-2-one)ruthenium(ii) tetraphenylborate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011665/ https://www.ncbi.nlm.nih.gov/pubmed/21589253 http://dx.doi.org/10.1107/S1600536810046064 |
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