(2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate

The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si—C bond distances are in the range 1.858 (2)–1.880 (2) Å and an intra­molecular O—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Nelson, Bjoern, Schürmann, Markus, Preut, Hans, Hiersemann, Martin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011670/
https://www.ncbi.nlm.nih.gov/pubmed/21589408
http://dx.doi.org/10.1107/S1600536810044818
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author Nelson, Bjoern
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
author_facet Nelson, Bjoern
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
author_sort Nelson, Bjoern
collection PubMed
description The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si—C bond distances are in the range 1.858 (2)–1.880 (2) Å and an intra­molecular O—H⋯O hydrogen bond helps to stabilize the mol­ecular conformation.
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spelling pubmed-30116702010-12-30 (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate Nelson, Bjoern Schürmann, Markus Preut, Hans Hiersemann, Martin Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si—C bond distances are in the range 1.858 (2)–1.880 (2) Å and an intra­molecular O—H⋯O hydrogen bond helps to stabilize the mol­ecular conformation. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011670/ /pubmed/21589408 http://dx.doi.org/10.1107/S1600536810044818 Text en © Nelson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nelson, Bjoern
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
(2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title_full (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title_fullStr (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title_full_unstemmed (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title_short (2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
title_sort (2sr,3sr)-isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011670/
https://www.ncbi.nlm.nih.gov/pubmed/21589408
http://dx.doi.org/10.1107/S1600536810044818
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