2-(Methyl­sulfin­yl)benzamide

In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl­sulfan­yl)benzamide using NaOCl with 2,2,6,6-tetra­methyl­piperidyl-1-oxy (TEMPO) as the catalyst, mol­ecules are linked via inter­molecular N—H⋯O(amide) hydrogen bonds, forming centrosymmetric amide–amid...

Descripción completa

Detalles Bibliográficos
Autor principal: Yan, Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011674/
https://www.ncbi.nlm.nih.gov/pubmed/21589589
http://dx.doi.org/10.1107/S1600536810046660
_version_ 1782194999173054464
author Yan, Zhou
author_facet Yan, Zhou
author_sort Yan, Zhou
collection PubMed
description In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl­sulfan­yl)benzamide using NaOCl with 2,2,6,6-tetra­methyl­piperidyl-1-oxy (TEMPO) as the catalyst, mol­ecules are linked via inter­molecular N—H⋯O(amide) hydrogen bonds, forming centrosymmetric amide–amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide–sulfinyl N—H⋯O hydrogen bonds. The benzene ring forms a dihedral angle of 25.6 (2)° with the amide group
format Text
id pubmed-3011674
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116742010-12-30 2-(Methyl­sulfin­yl)benzamide Yan, Zhou Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl­sulfan­yl)benzamide using NaOCl with 2,2,6,6-tetra­methyl­piperidyl-1-oxy (TEMPO) as the catalyst, mol­ecules are linked via inter­molecular N—H⋯O(amide) hydrogen bonds, forming centrosymmetric amide–amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide–sulfinyl N—H⋯O hydrogen bonds. The benzene ring forms a dihedral angle of 25.6 (2)° with the amide group International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011674/ /pubmed/21589589 http://dx.doi.org/10.1107/S1600536810046660 Text en © Zhou Yan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yan, Zhou
2-(Methyl­sulfin­yl)benzamide
title 2-(Methyl­sulfin­yl)benzamide
title_full 2-(Methyl­sulfin­yl)benzamide
title_fullStr 2-(Methyl­sulfin­yl)benzamide
title_full_unstemmed 2-(Methyl­sulfin­yl)benzamide
title_short 2-(Methyl­sulfin­yl)benzamide
title_sort 2-(methyl­sulfin­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011674/
https://www.ncbi.nlm.nih.gov/pubmed/21589589
http://dx.doi.org/10.1107/S1600536810046660
work_keys_str_mv AT yanzhou 2methylsulfinylbenzamide

Ejemplares similares