(2,2′-Biquinoline-κ(2) N,N′)dibromido­zinc(II)

In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the 2,2′-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak inter­molecular C—H⋯Br hydrogen bonds and extensive int...

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Detalles Bibliográficos
Autores principales: Saravani, Hamideh, Rezvani, Ali Reza, Akbarzadeh Torbati, Niloufar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011677/
https://www.ncbi.nlm.nih.gov/pubmed/21589297
http://dx.doi.org/10.1107/S1600536810047434
Descripción
Sumario:In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the 2,2′-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak inter­molecular C—H⋯Br hydrogen bonds and extensive inter­molecular π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.775 (4), 3.748 (4), 3.735 (4), 3.538 (4), 3.678 (4) and 3.513 (4) Å].

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