Cargando…
(2,2′-Biquinoline-κ(2) N,N′)dibromidozinc(II)
In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the 2,2′-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak intermolecular C—H⋯Br hydrogen bonds and extensive int...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011677/ https://www.ncbi.nlm.nih.gov/pubmed/21589297 http://dx.doi.org/10.1107/S1600536810047434 |
| _version_ | 1782194999886086144 |
|---|---|
| author | Saravani, Hamideh Rezvani, Ali Reza Akbarzadeh Torbati, Niloufar |
| author_facet | Saravani, Hamideh Rezvani, Ali Reza Akbarzadeh Torbati, Niloufar |
| author_sort | Saravani, Hamideh |
| collection | PubMed |
| description | In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the 2,2′-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak intermolecular C—H⋯Br hydrogen bonds and extensive intermolecular π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.775 (4), 3.748 (4), 3.735 (4), 3.538 (4), 3.678 (4) and 3.513 (4) Å]. |
| format | Text |
| id | pubmed-3011677 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30116772010-12-30 (2,2′-Biquinoline-κ(2) N,N′)dibromidozinc(II) Saravani, Hamideh Rezvani, Ali Reza Akbarzadeh Torbati, Niloufar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the 2,2′-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak intermolecular C—H⋯Br hydrogen bonds and extensive intermolecular π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.775 (4), 3.748 (4), 3.735 (4), 3.538 (4), 3.678 (4) and 3.513 (4) Å]. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011677/ /pubmed/21589297 http://dx.doi.org/10.1107/S1600536810047434 Text en © Saravani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Saravani, Hamideh Rezvani, Ali Reza Akbarzadeh Torbati, Niloufar (2,2′-Biquinoline-κ(2) N,N′)dibromidozinc(II) |
| title | (2,2′-Biquinoline-κ(2)
N,N′)dibromidozinc(II) |
| title_full | (2,2′-Biquinoline-κ(2)
N,N′)dibromidozinc(II) |
| title_fullStr | (2,2′-Biquinoline-κ(2)
N,N′)dibromidozinc(II) |
| title_full_unstemmed | (2,2′-Biquinoline-κ(2)
N,N′)dibromidozinc(II) |
| title_short | (2,2′-Biquinoline-κ(2)
N,N′)dibromidozinc(II) |
| title_sort | (2,2′-biquinoline-κ(2)
n,n′)dibromidozinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011677/ https://www.ncbi.nlm.nih.gov/pubmed/21589297 http://dx.doi.org/10.1107/S1600536810047434 |
| work_keys_str_mv | AT saravanihamideh 22biquinolinek2nndibromidozincii AT rezvanialireza 22biquinolinek2nndibromidozincii AT akbarzadehtorbatiniloufar 22biquinolinek2nndibromidozincii |