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Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]erbium(III)} monohydrate
The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hydroxyphenyl)acetate (PAA) anions, two 4,4′-bipyridine (bipy) molecules, two coordinated water molecules and one solvent water molecule. The cen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011679/ https://www.ncbi.nlm.nih.gov/pubmed/21589217 http://dx.doi.org/10.1107/S1600536810044752 |
Sumario: | The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hydroxyphenyl)acetate (PAA) anions, two 4,4′-bipyridine (bipy) molecules, two coordinated water molecules and one solvent water molecule. The central Er(III) atoms are nine-coordinated. The coordination environment includes six O atoms from three PAA anions, one bridging O atom from a PAA anion, one O atom from a water molecule and an N atom from a bipy ligand in a distorted tricapped trigonal–prismatic geometry. The occurrence of numerous O—H⋯O and O—H⋯N hydrogen bonds involving coordinated and noncoordinated water as well as bipy groups builds up an intricate three-dimensional network. |
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