Cargando…
Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]erbium(III)} monohydrate
The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hydroxyphenyl)acetate (PAA) anions, two 4,4′-bipyridine (bipy) molecules, two coordinated water molecules and one solvent water molecule. The cen...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011679/ https://www.ncbi.nlm.nih.gov/pubmed/21589217 http://dx.doi.org/10.1107/S1600536810044752 |
_version_ | 1782195000373673984 |
---|---|
author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_sort | Liu, Jia-Lu |
collection | PubMed |
description | The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hydroxyphenyl)acetate (PAA) anions, two 4,4′-bipyridine (bipy) molecules, two coordinated water molecules and one solvent water molecule. The central Er(III) atoms are nine-coordinated. The coordination environment includes six O atoms from three PAA anions, one bridging O atom from a PAA anion, one O atom from a water molecule and an N atom from a bipy ligand in a distorted tricapped trigonal–prismatic geometry. The occurrence of numerous O—H⋯O and O—H⋯N hydrogen bonds involving coordinated and noncoordinated water as well as bipy groups builds up an intricate three-dimensional network. |
format | Text |
id | pubmed-3011679 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116792010-12-30 Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]erbium(III)} monohydrate Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hydroxyphenyl)acetate (PAA) anions, two 4,4′-bipyridine (bipy) molecules, two coordinated water molecules and one solvent water molecule. The central Er(III) atoms are nine-coordinated. The coordination environment includes six O atoms from three PAA anions, one bridging O atom from a PAA anion, one O atom from a water molecule and an N atom from a bipy ligand in a distorted tricapped trigonal–prismatic geometry. The occurrence of numerous O—H⋯O and O—H⋯N hydrogen bonds involving coordinated and noncoordinated water as well as bipy groups builds up an intricate three-dimensional network. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011679/ /pubmed/21589217 http://dx.doi.org/10.1107/S1600536810044752 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]erbium(III)} monohydrate |
title | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]erbium(III)} monohydrate |
title_full | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]erbium(III)} monohydrate |
title_fullStr | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]erbium(III)} monohydrate |
title_full_unstemmed | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]erbium(III)} monohydrate |
title_short | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]erbium(III)} monohydrate |
title_sort | bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o,o′:o;κ(3)
o:o,o′-bis{aqua(4,4′-bipyridine-κn)[2-(4-hydroxyphenyl)acetato-κ(2)
o,o′]erbium(iii)} monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011679/ https://www.ncbi.nlm.nih.gov/pubmed/21589217 http://dx.doi.org/10.1107/S1600536810044752 |
work_keys_str_mv | AT liujialu bism24hydroxyphenylacetatok3oook3ooobisaqua44bipyridinekn24hydroxyphenylacetatok2ooerbiumiiimonohydrate AT liujianfeng bism24hydroxyphenylacetatok3oook3ooobisaqua44bipyridinekn24hydroxyphenylacetatok2ooerbiumiiimonohydrate AT zhaoguoliang bism24hydroxyphenylacetatok3oook3ooobisaqua44bipyridinekn24hydroxyphenylacetatok2ooerbiumiiimonohydrate |