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1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)

In the title salt, (C(8)H(15)N(3))[CdBr(4)], four Br atoms coordinate the Cd(II) atom in a distorted tetra­hedral geometry. In the crystal, weak N—H⋯Br inter­actions connect the anion to three symmetry-related cations. The crystal structure also displays very weak C—H⋯Br inter­actions.

Detalles Bibliográficos
Autor principal: Wei, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011683/
https://www.ncbi.nlm.nih.gov/pubmed/21589331
http://dx.doi.org/10.1107/S1600536810047495
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author Wei, Bin
author_facet Wei, Bin
author_sort Wei, Bin
collection PubMed
description In the title salt, (C(8)H(15)N(3))[CdBr(4)], four Br atoms coordinate the Cd(II) atom in a distorted tetra­hedral geometry. In the crystal, weak N—H⋯Br inter­actions connect the anion to three symmetry-related cations. The crystal structure also displays very weak C—H⋯Br inter­actions.
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spelling pubmed-30116832010-12-30 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II) Wei, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(8)H(15)N(3))[CdBr(4)], four Br atoms coordinate the Cd(II) atom in a distorted tetra­hedral geometry. In the crystal, weak N—H⋯Br inter­actions connect the anion to three symmetry-related cations. The crystal structure also displays very weak C—H⋯Br inter­actions. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011683/ /pubmed/21589331 http://dx.doi.org/10.1107/S1600536810047495 Text en © Bin Wei 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Bin
1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title_full 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title_fullStr 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title_full_unstemmed 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title_short 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(II)
title_sort 1-cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocadmate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011683/
https://www.ncbi.nlm.nih.gov/pubmed/21589331
http://dx.doi.org/10.1107/S1600536810047495
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