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Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]

There are three Ag(I) cations, three p-toluene­sulfonate (pts) anions, three hexa­methyl­ene­tetra­mine (hmt) mol­ecules and four water mol­ecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show posi...

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Detalles Bibliográficos
Autores principales: Wu, Hua, Shang, Meng-Xiang, ShangGuan, Shao-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011686/
https://www.ncbi.nlm.nih.gov/pubmed/21589326
http://dx.doi.org/10.1107/S1600536810048567
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author Wu, Hua
Shang, Meng-Xiang
ShangGuan, Shao-Ping
author_facet Wu, Hua
Shang, Meng-Xiang
ShangGuan, Shao-Ping
author_sort Wu, Hua
collection PubMed
description There are three Ag(I) cations, three p-toluene­sulfonate (pts) anions, three hexa­methyl­ene­tetra­mine (hmt) mol­ecules and four water mol­ecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag(I) ion is coordinated by three hmt mol­ecules in an approximate trigonal–planar AgN(3) arrangement. In each case, longer Ag—O bonds to a water mol­ecule and a pts anion complete a distorted trigonal–bipyramidal AgN(3)O(2) geometry for the metal ion. In the crystal, the bridging hmt mol­ecules and pts ions generate a wave-like layer parallel to (001) and O—H⋯O hydrogen-bonding inter­actions consolidate the packing.
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spelling pubmed-30116862010-12-30 Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate] Wu, Hua Shang, Meng-Xiang ShangGuan, Shao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are three Ag(I) cations, three p-toluene­sulfonate (pts) anions, three hexa­methyl­ene­tetra­mine (hmt) mol­ecules and four water mol­ecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag(I) ion is coordinated by three hmt mol­ecules in an approximate trigonal–planar AgN(3) arrangement. In each case, longer Ag—O bonds to a water mol­ecule and a pts anion complete a distorted trigonal–bipyramidal AgN(3)O(2) geometry for the metal ion. In the crystal, the bridging hmt mol­ecules and pts ions generate a wave-like layer parallel to (001) and O—H⋯O hydrogen-bonding inter­actions consolidate the packing. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011686/ /pubmed/21589326 http://dx.doi.org/10.1107/S1600536810048567 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Hua
Shang, Meng-Xiang
ShangGuan, Shao-Ping
Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title_full Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title_fullStr Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title_full_unstemmed Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title_short Poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]
title_sort poly[[aqua­tris­(μ(3)-hexa­methyl­ene­tetra­mine-κ(3) n,n′,n′′)tris­(p-toluene­sulfonato-κo)tris­ilver(i)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011686/
https://www.ncbi.nlm.nih.gov/pubmed/21589326
http://dx.doi.org/10.1107/S1600536810048567
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