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Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3) N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate]
There are three Ag(I) cations, three p-toluenesulfonate (pts) anions, three hexamethylenetetramine (hmt) molecules and four water molecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show posi...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011686/ https://www.ncbi.nlm.nih.gov/pubmed/21589326 http://dx.doi.org/10.1107/S1600536810048567 |
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author | Wu, Hua Shang, Meng-Xiang ShangGuan, Shao-Ping |
author_facet | Wu, Hua Shang, Meng-Xiang ShangGuan, Shao-Ping |
author_sort | Wu, Hua |
collection | PubMed |
description | There are three Ag(I) cations, three p-toluenesulfonate (pts) anions, three hexamethylenetetramine (hmt) molecules and four water molecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag(I) ion is coordinated by three hmt molecules in an approximate trigonal–planar AgN(3) arrangement. In each case, longer Ag—O bonds to a water molecule and a pts anion complete a distorted trigonal–bipyramidal AgN(3)O(2) geometry for the metal ion. In the crystal, the bridging hmt molecules and pts ions generate a wave-like layer parallel to (001) and O—H⋯O hydrogen-bonding interactions consolidate the packing. |
format | Text |
id | pubmed-3011686 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116862010-12-30 Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3) N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] Wu, Hua Shang, Meng-Xiang ShangGuan, Shao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are three Ag(I) cations, three p-toluenesulfonate (pts) anions, three hexamethylenetetramine (hmt) molecules and four water molecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag(I) ion is coordinated by three hmt molecules in an approximate trigonal–planar AgN(3) arrangement. In each case, longer Ag—O bonds to a water molecule and a pts anion complete a distorted trigonal–bipyramidal AgN(3)O(2) geometry for the metal ion. In the crystal, the bridging hmt molecules and pts ions generate a wave-like layer parallel to (001) and O—H⋯O hydrogen-bonding interactions consolidate the packing. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011686/ /pubmed/21589326 http://dx.doi.org/10.1107/S1600536810048567 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Hua Shang, Meng-Xiang ShangGuan, Shao-Ping Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3) N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title | Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title_full | Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title_fullStr | Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title_full_unstemmed | Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title_short | Poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate] |
title_sort | poly[[aquatris(μ(3)-hexamethylenetetramine-κ(3)
n,n′,n′′)tris(p-toluenesulfonato-κo)trisilver(i)] trihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011686/ https://www.ncbi.nlm.nih.gov/pubmed/21589326 http://dx.doi.org/10.1107/S1600536810048567 |
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