Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate

In the title salt, [ZnCl(C(6)H(7)N(3))(2)]Cl·2H(2)O, the pyridine-2-carboximidamide ligands chelate to the Zn(II) atom, which is also coordinated by a Cl atom. The Zn(II) atom shows a trigonal–bipyramidal coordination, with the pyridyl N atoms occupying the axial positions. The cation, anion and wat...

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Detalles Bibliográficos
Autores principales: Dong, Guang-Hua, Xue, Rui-De, Li, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011688/
https://www.ncbi.nlm.nih.gov/pubmed/21589248
http://dx.doi.org/10.1107/S1600536810045848
Descripción
Sumario:In the title salt, [ZnCl(C(6)H(7)N(3))(2)]Cl·2H(2)O, the pyridine-2-carboximidamide ligands chelate to the Zn(II) atom, which is also coordinated by a Cl atom. The Zn(II) atom shows a trigonal–bipyramidal coordination, with the pyridyl N atoms occupying the axial positions. The cation, anion and water mol­ecules are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds into a three-dimensional structure.

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