Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate

In the title salt, [ZnCl(C(6)H(7)N(3))(2)]Cl·2H(2)O, the pyridine-2-carboximidamide ligands chelate to the Zn(II) atom, which is also coordinated by a Cl atom. The Zn(II) atom shows a trigonal–bipyramidal coordination, with the pyridyl N atoms occupying the axial positions. The cation, anion and wat...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Guang-Hua, Xue, Rui-De, Li, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011688/
https://www.ncbi.nlm.nih.gov/pubmed/21589248
http://dx.doi.org/10.1107/S1600536810045848
_version_ 1782195002484457472
author Dong, Guang-Hua
Xue, Rui-De
Li, Jing
author_facet Dong, Guang-Hua
Xue, Rui-De
Li, Jing
author_sort Dong, Guang-Hua
collection PubMed
description In the title salt, [ZnCl(C(6)H(7)N(3))(2)]Cl·2H(2)O, the pyridine-2-carboximidamide ligands chelate to the Zn(II) atom, which is also coordinated by a Cl atom. The Zn(II) atom shows a trigonal–bipyramidal coordination, with the pyridyl N atoms occupying the axial positions. The cation, anion and water mol­ecules are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds into a three-dimensional structure.
format Text
id pubmed-3011688
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116882010-12-30 Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate Dong, Guang-Hua Xue, Rui-De Li, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [ZnCl(C(6)H(7)N(3))(2)]Cl·2H(2)O, the pyridine-2-carboximidamide ligands chelate to the Zn(II) atom, which is also coordinated by a Cl atom. The Zn(II) atom shows a trigonal–bipyramidal coordination, with the pyridyl N atoms occupying the axial positions. The cation, anion and water mol­ecules are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds into a three-dimensional structure. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011688/ /pubmed/21589248 http://dx.doi.org/10.1107/S1600536810045848 Text en © Dong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Guang-Hua
Xue, Rui-De
Li, Jing
Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title_full Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title_fullStr Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title_full_unstemmed Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title_short Chlorido(pyridine-2-carboximidamide-κ(2) N (1),N (2))zinc(II) chloride dihydrate
title_sort chlorido(pyridine-2-carboximidamide-κ(2) n (1),n (2))zinc(ii) chloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011688/
https://www.ncbi.nlm.nih.gov/pubmed/21589248
http://dx.doi.org/10.1107/S1600536810045848
work_keys_str_mv AT dongguanghua chloridopyridine2carboximidamidek2n1n2zinciichloridedihydrate
AT xueruide chloridopyridine2carboximidamidek2n1n2zinciichloridedihydrate
AT lijing chloridopyridine2carboximidamidek2n1n2zinciichloridedihydrate

Ejemplares similares