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catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)]
The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011691/ https://www.ncbi.nlm.nih.gov/pubmed/21589352 http://dx.doi.org/10.1107/S1600536810049330 |
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author | Zhang, Ke-Ke Fang, Xin Yu, Hai-Yang Ke, Hua Wang, Jun-Dong |
author_facet | Zhang, Ke-Ke Fang, Xin Yu, Hai-Yang Ke, Hua Wang, Jun-Dong |
author_sort | Zhang, Ke-Ke |
collection | PubMed |
description | The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding interactions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π interactions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H⋯O and N—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-3011691 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116912010-12-30 catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] Zhang, Ke-Ke Fang, Xin Yu, Hai-Yang Ke, Hua Wang, Jun-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothiazole-6-carboxylate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding interactions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π interactions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H⋯O and N—H⋯N hydrogen bonds. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011691/ /pubmed/21589352 http://dx.doi.org/10.1107/S1600536810049330 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Ke-Ke Fang, Xin Yu, Hai-Yang Ke, Hua Wang, Jun-Dong catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title |
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title_full |
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title_fullStr |
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title_full_unstemmed |
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title_short |
catena-Poly[lead(II)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
title_sort | catena-poly[lead(ii)-bis(μ-2-amino-1,3-benzothiazole-6-carboxylato)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011691/ https://www.ncbi.nlm.nih.gov/pubmed/21589352 http://dx.doi.org/10.1107/S1600536810049330 |
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