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catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]

The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two...

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Detalles Bibliográficos
Autores principales: Zhang, Ke-Ke, Fang, Xin, Yu, Hai-Yang, Ke, Hua, Wang, Jun-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011691/
https://www.ncbi.nlm.nih.gov/pubmed/21589352
http://dx.doi.org/10.1107/S1600536810049330
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author Zhang, Ke-Ke
Fang, Xin
Yu, Hai-Yang
Ke, Hua
Wang, Jun-Dong
author_facet Zhang, Ke-Ke
Fang, Xin
Yu, Hai-Yang
Ke, Hua
Wang, Jun-Dong
author_sort Zhang, Ke-Ke
collection PubMed
description The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding inter­actions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π inter­actions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H⋯O and N—H⋯N hydrogen bonds.
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spelling pubmed-30116912010-12-30 catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)] Zhang, Ke-Ke Fang, Xin Yu, Hai-Yang Ke, Hua Wang, Jun-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Pb(C(8)H(5)N(2)O(2)S)(2)](n), consists of one Pb(II) ion located on a crystallographic twofold axis and two symmetry-related 2-amino-1,3-benzothia­zole-6-carboxyl­ate (ABTC) ligands. The central Pb(II) ion has a (4 + 2) coordination by four O atoms of the two ABTC ligands and two weaker Pb—S bonding inter­actions (Pb—S secondary bonds) from S atoms of other two neighbouring ABTC ligands. These bonds link the metal ions into zigzag chains along the c axis, which, in turn, aggregate through π–π inter­actions [centroid–centroid distance = 3.7436 Å] between ABTC rings and N—H⋯O and N—H⋯N hydrogen bonds. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011691/ /pubmed/21589352 http://dx.doi.org/10.1107/S1600536810049330 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ke-Ke
Fang, Xin
Yu, Hai-Yang
Ke, Hua
Wang, Jun-Dong
catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title_full catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title_fullStr catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title_full_unstemmed catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title_short catena-Poly[lead(II)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
title_sort catena-poly[lead(ii)-bis­(μ-2-amino-1,3-benzothia­zole-6-carboxyl­ato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011691/
https://www.ncbi.nlm.nih.gov/pubmed/21589352
http://dx.doi.org/10.1107/S1600536810049330
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