2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide

In the crystal, the inversely oriented mol­ecules of the title compound, C(15)H(9)BF(2)O(3), form stacks along the a axis via π–π inter­actions between parallel phenyl­chromenium fragments. Linked by a network of C—H⋯F inter­actions, the stacks form layers in the ac plane that are dispersively stabi...

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Detalles Bibliográficos
Autores principales: Wera, Michał, Roshal, Alexander D., Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011699/
https://www.ncbi.nlm.nih.gov/pubmed/21589624
http://dx.doi.org/10.1107/S1600536810048919
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author Wera, Michał
Roshal, Alexander D.
Błażejowski, Jerzy
author_facet Wera, Michał
Roshal, Alexander D.
Błażejowski, Jerzy
author_sort Wera, Michał
collection PubMed
description In the crystal, the inversely oriented mol­ecules of the title compound, C(15)H(9)BF(2)O(3), form stacks along the a axis via π–π inter­actions between parallel phenyl­chromenium fragments. Linked by a network of C—H⋯F inter­actions, the stacks form layers in the ac plane that are dispersively stabilized in the crystal structure. Two F atoms bonded to the B atom are located in the plane perpendicular to the planar skeleton of the mol­ecule made rigid by two intra­molecular C—H⋯O inter­actions.
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spelling pubmed-30116992010-12-30 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide Wera, Michał Roshal, Alexander D. Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal, the inversely oriented mol­ecules of the title compound, C(15)H(9)BF(2)O(3), form stacks along the a axis via π–π inter­actions between parallel phenyl­chromenium fragments. Linked by a network of C—H⋯F inter­actions, the stacks form layers in the ac plane that are dispersively stabilized in the crystal structure. Two F atoms bonded to the B atom are located in the plane perpendicular to the planar skeleton of the mol­ecule made rigid by two intra­molecular C—H⋯O inter­actions. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011699/ /pubmed/21589624 http://dx.doi.org/10.1107/S1600536810048919 Text en © Wera et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wera, Michał
Roshal, Alexander D.
Błażejowski, Jerzy
2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title_full 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title_fullStr 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title_full_unstemmed 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title_short 2,2-Difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
title_sort 2,2-difluoro-4-phenyl-1,3,2-dioxaborolo[4,5-c]chromen-5-ium-2-ide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011699/
https://www.ncbi.nlm.nih.gov/pubmed/21589624
http://dx.doi.org/10.1107/S1600536810048919
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