Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]

In the title coordination polymer, {[Eu(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Eu(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate (hpc) trianion, two monodentate hpc anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic coordination ge...

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Detalles Bibliográficos
Autores principales: Lv, Dong-Yu, Gao, Zhu-Qing, Gu, Jin-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011704/
https://www.ncbi.nlm.nih.gov/pubmed/21589349
http://dx.doi.org/10.1107/S1600536810048518
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author Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
author_facet Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
author_sort Lv, Dong-Yu
collection PubMed
description In the title coordination polymer, {[Eu(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Eu(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate (hpc) trianion, two monodentate hpc anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic coordination geometry. The hpc ligands bridge adjacent Eu(III) ions, forming infinite double chains. Adjacent chains are further connected by hpc ligands into sheets. O—H⋯O hydrogen bonds then generate a three-dimensional supra­molecular framework.
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spelling pubmed-30117042010-12-30 Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate] Lv, Dong-Yu Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Eu(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Eu(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate (hpc) trianion, two monodentate hpc anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic coordination geometry. The hpc ligands bridge adjacent Eu(III) ions, forming infinite double chains. Adjacent chains are further connected by hpc ligands into sheets. O—H⋯O hydrogen bonds then generate a three-dimensional supra­molecular framework. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011704/ /pubmed/21589349 http://dx.doi.org/10.1107/S1600536810048518 Text en © Lv et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title_full Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title_fullStr Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title_full_unstemmed Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title_short Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(III)] monohydrate]
title_sort poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)europium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011704/
https://www.ncbi.nlm.nih.gov/pubmed/21589349
http://dx.doi.org/10.1107/S1600536810048518
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AT gaozhuqing polytriaquam34oxidopyridine26dicarboxylatoeuropiumiiimonohydrate
AT gujinzhong polytriaquam34oxidopyridine26dicarboxylatoeuropiumiiimonohydrate

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