N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide

In the title compound, C(15)H(24)F(2)N(3)O(2)P, the phosphoryl and carbonyl groups adopt anti positions relative to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar. In the crystal, adjacent mol­ecules are linked via N—H⋯O=...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011709/
https://www.ncbi.nlm.nih.gov/pubmed/21589456
http://dx.doi.org/10.1107/S1600536810045927
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author Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_facet Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title compound, C(15)H(24)F(2)N(3)O(2)P, the phosphoryl and carbonyl groups adopt anti positions relative to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P and N—H⋯O=C hydrogen bonds into an extended chain parallel to the a axis. The crystal studied was a non-merohedral twin with a minor twin component of 36.4 (1)%.
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spelling pubmed-30117092010-12-30 N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(24)F(2)N(3)O(2)P, the phosphoryl and carbonyl groups adopt anti positions relative to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P and N—H⋯O=C hydrogen bonds into an extended chain parallel to the a axis. The crystal studied was a non-merohedral twin with a minor twin component of 36.4 (1)%. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011709/ /pubmed/21589456 http://dx.doi.org/10.1107/S1600536810045927 Text en © Pourayoubi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_full N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_fullStr N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_full_unstemmed N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_short N,N′-Di-tert-butyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_sort n,n′-di-tert-butyl-n′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011709/
https://www.ncbi.nlm.nih.gov/pubmed/21589456
http://dx.doi.org/10.1107/S1600536810045927
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