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[N-(3-Methoxy-2-oxidobenzylidene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex molecules and two uncoordinated water molecules. In each complex molecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,1...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011713/ https://www.ncbi.nlm.nih.gov/pubmed/21589245 http://dx.doi.org/10.1107/S160053681004554X |
Sumario: | The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex molecules and two uncoordinated water molecules. In each complex molecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu—N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonds together with C—H⋯π interactions result in a three-dimensional supramolecular structure. |
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