[N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate

The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol­ecules and two uncoordinated water mol­ecules. In each complex mol­ecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,1...

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Detalles Bibliográficos
Autores principales: Huang, Lei, Dong, Jianfang, Jing, Buqin, Li, Lianzhi, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011713/
https://www.ncbi.nlm.nih.gov/pubmed/21589245
http://dx.doi.org/10.1107/S160053681004554X
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author Huang, Lei
Dong, Jianfang
Jing, Buqin
Li, Lianzhi
Wang, Daqi
author_facet Huang, Lei
Dong, Jianfang
Jing, Buqin
Li, Lianzhi
Wang, Daqi
author_sort Huang, Lei
collection PubMed
description The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol­ecules and two uncoordinated water mol­ecules. In each complex mol­ecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu—N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with C—H⋯π inter­actions result in a three-dimensional supra­molecular structure.
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spelling pubmed-30117132010-12-30 [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate Huang, Lei Dong, Jianfang Jing, Buqin Li, Lianzhi Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol­ecules and two uncoordinated water mol­ecules. In each complex mol­ecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu—N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with C—H⋯π inter­actions result in a three-dimensional supra­molecular structure. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011713/ /pubmed/21589245 http://dx.doi.org/10.1107/S160053681004554X Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Lei
Dong, Jianfang
Jing, Buqin
Li, Lianzhi
Wang, Daqi
[N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_full [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_fullStr [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_full_unstemmed [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_short [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_sort [n-(3-meth­oxy-2-oxidobenzyl­idene-κo (2))leucinato-κ(2) n,o](1,10-phenanthroline-κ(2) n,n′)copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011713/
https://www.ncbi.nlm.nih.gov/pubmed/21589245
http://dx.doi.org/10.1107/S160053681004554X
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