catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]

In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis­(imidazol-1-yl)benzene ligands, generating a distorted tetra­hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, whic...

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Detalles Bibliográficos
Autores principales: Nan, Yi, Yuan, Ling, Xu, Cheng-Bi, Nan, Shan-Ji, Niu, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011715/
https://www.ncbi.nlm.nih.gov/pubmed/21589220
http://dx.doi.org/10.1107/S1600536810044429
Descripción
Sumario:In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis­(imidazol-1-yl)benzene ligands, generating a distorted tetra­hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82 (13)°.

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