catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]

In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis­(imidazol-1-yl)benzene ligands, generating a distorted tetra­hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, whic...

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Detalles Bibliográficos
Autores principales: Nan, Yi, Yuan, Ling, Xu, Cheng-Bi, Nan, Shan-Ji, Niu, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011715/
https://www.ncbi.nlm.nih.gov/pubmed/21589220
http://dx.doi.org/10.1107/S1600536810044429
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author Nan, Yi
Yuan, Ling
Xu, Cheng-Bi
Nan, Shan-Ji
Niu, Yang
author_facet Nan, Yi
Yuan, Ling
Xu, Cheng-Bi
Nan, Shan-Ji
Niu, Yang
author_sort Nan, Yi
collection PubMed
description In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis­(imidazol-1-yl)benzene ligands, generating a distorted tetra­hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82 (13)°.
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spelling pubmed-30117152010-12-30 catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene] Nan, Yi Yuan, Ling Xu, Cheng-Bi Nan, Shan-Ji Niu, Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis­(imidazol-1-yl)benzene ligands, generating a distorted tetra­hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82 (13)°. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011715/ /pubmed/21589220 http://dx.doi.org/10.1107/S1600536810044429 Text en © Nan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nan, Yi
Yuan, Ling
Xu, Cheng-Bi
Nan, Shan-Ji
Niu, Yang
catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title_full catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title_fullStr catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title_full_unstemmed catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title_short catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(1H-imidazol-1-yl)benzene]
title_sort catena-poly[[dichloridozinc(ii)]-μ-1,4-bis­(1h-imidazol-1-yl)benzene]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011715/
https://www.ncbi.nlm.nih.gov/pubmed/21589220
http://dx.doi.org/10.1107/S1600536810044429
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AT niuyang catenapolydichloridozinciim14bis1himidazol1ylbenzene

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