Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)

The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho­rhom­bic form [Lu et al. (2006 ▶). Inorg. Chem. 45, 3538–3548]. The Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a dist...

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Autor principal: Zhang, Daopeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011716/
https://www.ncbi.nlm.nih.gov/pubmed/21589321
http://dx.doi.org/10.1107/S1600536810048270
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author Zhang, Daopeng
author_facet Zhang, Daopeng
author_sort Zhang, Daopeng
collection PubMed
description The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho­rhom­bic form [Lu et al. (2006 ▶). Inorg. Chem. 45, 3538–3548]. The Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter­molecular Mn⋯O(phenolate) distances of 2.752 (3) Å between pairs of inversion-related mol­ecules.
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spelling pubmed-30117162010-12-30 Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) Zhang, Daopeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho­rhom­bic form [Lu et al. (2006 ▶). Inorg. Chem. 45, 3538–3548]. The Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter­molecular Mn⋯O(phenolate) distances of 2.752 (3) Å between pairs of inversion-related mol­ecules. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011716/ /pubmed/21589321 http://dx.doi.org/10.1107/S1600536810048270 Text en © Daopeng Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Daopeng
Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title_full Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title_fullStr Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title_full_unstemmed Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title_short Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
title_sort monoclinic form of (cyanato-κn){2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) o,n,n′,o′}manganese(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011716/
https://www.ncbi.nlm.nih.gov/pubmed/21589321
http://dx.doi.org/10.1107/S1600536810048270
work_keys_str_mv AT zhangdaopeng monoclinicformofcyanatokn22ethane12diylbisnitrilomethylidynediphenolatok4onnomanganeseiii

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