Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide

Single crystals of the title compound, C(10)H(13)OS(+)·Br(−), were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydro­bromic acid and dimethyl­sulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C—C—C = 178.9 (2)°]. The sulfanium group...

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Detalles Bibliográficos
Autores principales: Cao, Zhiling, Liu, Weiwei, Yin, Fujun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011718/
https://www.ncbi.nlm.nih.gov/pubmed/21589491
http://dx.doi.org/10.1107/S1600536810046404
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author Cao, Zhiling
Liu, Weiwei
Yin, Fujun
author_facet Cao, Zhiling
Liu, Weiwei
Yin, Fujun
author_sort Cao, Zhiling
collection PubMed
description Single crystals of the title compound, C(10)H(13)OS(+)·Br(−), were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydro­bromic acid and dimethyl­sulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C—C—C = 178.9 (2)°]. The sulfanium group shows a trigonal–pyramidal geometry at the S atom. The crystal structure is stabil­ized by C—H⋯Br hydrogen-bonding inter­actions. Weak π–π inter­actions link adjacent phenyl rings [centroid–centroid distance = 3.946 (2) Å].
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spelling pubmed-30117182010-12-30 Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide Cao, Zhiling Liu, Weiwei Yin, Fujun Acta Crystallogr Sect E Struct Rep Online Organic Papers Single crystals of the title compound, C(10)H(13)OS(+)·Br(−), were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydro­bromic acid and dimethyl­sulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C—C—C = 178.9 (2)°]. The sulfanium group shows a trigonal–pyramidal geometry at the S atom. The crystal structure is stabil­ized by C—H⋯Br hydrogen-bonding inter­actions. Weak π–π inter­actions link adjacent phenyl rings [centroid–centroid distance = 3.946 (2) Å]. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011718/ /pubmed/21589491 http://dx.doi.org/10.1107/S1600536810046404 Text en © Cao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cao, Zhiling
Liu, Weiwei
Yin, Fujun
Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title_full Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title_fullStr Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title_full_unstemmed Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title_short Dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
title_sort dimeth­yl(2-oxo-2-phenyl­eth­yl)sulfanium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011718/
https://www.ncbi.nlm.nih.gov/pubmed/21589491
http://dx.doi.org/10.1107/S1600536810046404
work_keys_str_mv AT caozhiling dimethyl2oxo2phenylethylsulfaniumbromide
AT liuweiwei dimethyl2oxo2phenylethylsulfaniumbromide
AT yinfujun dimethyl2oxo2phenylethylsulfaniumbromide

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