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N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine
The complete molecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the molecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011719/ https://www.ncbi.nlm.nih.gov/pubmed/21589427 http://dx.doi.org/10.1107/S160053681004540X |
Sumario: | The complete molecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the molecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N—C—C—C = −12.4 (4)°]. In the crystal, a combination of π–π [pyridine–benzene centroid–centroid distance = 3.5670 (14) Å] and C—H⋯N contacts leads to supramolecular chains propagating in [010]. |
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