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N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine

The complete mol­ecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the mol­ecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethyl­ene bridge. Further, there is a small twist between the imine [N=C...

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Detalles Bibliográficos
Autores principales: Prasath, R., Bhavana, P., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011719/
https://www.ncbi.nlm.nih.gov/pubmed/21589427
http://dx.doi.org/10.1107/S160053681004540X
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author Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Prasath, R.
collection PubMed
description The complete mol­ecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the mol­ecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethyl­ene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N—C—C—C = −12.4 (4)°]. In the crystal, a combination of π–π [pyridine–benzene centroid–centroid distance = 3.5670 (14) Å] and C—H⋯N contacts leads to supra­molecular chains propagating in [010].
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spelling pubmed-30117192010-12-30 N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete mol­ecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the mol­ecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethyl­ene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N—C—C—C = −12.4 (4)°]. In the crystal, a combination of π–π [pyridine–benzene centroid–centroid distance = 3.5670 (14) Å] and C—H⋯N contacts leads to supra­molecular chains propagating in [010]. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011719/ /pubmed/21589427 http://dx.doi.org/10.1107/S160053681004540X Text en © Prasath et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title_full N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title_fullStr N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title_full_unstemmed N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title_short N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
title_sort n,n′-bis[(e)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011719/
https://www.ncbi.nlm.nih.gov/pubmed/21589427
http://dx.doi.org/10.1107/S160053681004540X
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