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N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine
The complete molecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the molecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011719/ https://www.ncbi.nlm.nih.gov/pubmed/21589427 http://dx.doi.org/10.1107/S160053681004540X |
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author | Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Prasath, R. |
collection | PubMed |
description | The complete molecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the molecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N—C—C—C = −12.4 (4)°]. In the crystal, a combination of π–π [pyridine–benzene centroid–centroid distance = 3.5670 (14) Å] and C—H⋯N contacts leads to supramolecular chains propagating in [010]. |
format | Text |
id | pubmed-3011719 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117192010-12-30 N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete molecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the molecule is evident [C—N—C—C torsion angle = −147.0 (3)°] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N—C—C—C = −12.4 (4)°]. In the crystal, a combination of π–π [pyridine–benzene centroid–centroid distance = 3.5670 (14) Å] and C—H⋯N contacts leads to supramolecular chains propagating in [010]. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011719/ /pubmed/21589427 http://dx.doi.org/10.1107/S160053681004540X Text en © Prasath et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title |
N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title_full |
N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title_fullStr |
N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title_full_unstemmed |
N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title_short |
N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
title_sort | n,n′-bis[(e)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011719/ https://www.ncbi.nlm.nih.gov/pubmed/21589427 http://dx.doi.org/10.1107/S160053681004540X |
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