3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione

The title spiro­oxindole compound, C(26)H(23)N(3)O(3), was prepared by the reaction of isatin, 3-methyl-1-phenyl-2-pyrazolin-5-one and 5,5-dimethyl­cyclo­hexane-1,3-dione in an ethanol solution. The fused cyclo­hexene ring adopts an envelope conformation. The dihedral angle between the aromatic and...

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Detalles Bibliográficos
Autores principales: Zhao, Li-Qin, Li, Bin, Li, Yi-Qun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011720/
https://www.ncbi.nlm.nih.gov/pubmed/21589419
http://dx.doi.org/10.1107/S1600536810045253
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author Zhao, Li-Qin
Li, Bin
Li, Yi-Qun
author_facet Zhao, Li-Qin
Li, Bin
Li, Yi-Qun
author_sort Zhao, Li-Qin
collection PubMed
description The title spiro­oxindole compound, C(26)H(23)N(3)O(3), was prepared by the reaction of isatin, 3-methyl-1-phenyl-2-pyrazolin-5-one and 5,5-dimethyl­cyclo­hexane-1,3-dione in an ethanol solution. The fused cyclo­hexene ring adopts an envelope conformation. The dihedral angle between the aromatic and pyrazoline rings is 23.70 (8)°. An intra­molecular C—H⋯O inter­action occurs. The crystal structure is stabilized by N—H⋯N hydrogen-bonding inter­actions, leading to a zigzag chain along the b axis.
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spelling pubmed-30117202010-12-30 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione Zhao, Li-Qin Li, Bin Li, Yi-Qun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title spiro­oxindole compound, C(26)H(23)N(3)O(3), was prepared by the reaction of isatin, 3-methyl-1-phenyl-2-pyrazolin-5-one and 5,5-dimethyl­cyclo­hexane-1,3-dione in an ethanol solution. The fused cyclo­hexene ring adopts an envelope conformation. The dihedral angle between the aromatic and pyrazoline rings is 23.70 (8)°. An intra­molecular C—H⋯O inter­action occurs. The crystal structure is stabilized by N—H⋯N hydrogen-bonding inter­actions, leading to a zigzag chain along the b axis. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011720/ /pubmed/21589419 http://dx.doi.org/10.1107/S1600536810045253 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Li-Qin
Li, Bin
Li, Yi-Qun
3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title_full 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title_fullStr 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title_full_unstemmed 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title_short 3′,7′,7′-Trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1H,4H-pyrazolo­[3,4-b]chromene)]-2,5′-dione
title_sort 3′,7′,7′-trimethyl-1′-phenyl-5′,6′,7′,8′-tetra­hydro­spiro­[indoline-3,4′-(1h,4h-pyrazolo­[3,4-b]chromene)]-2,5′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011720/
https://www.ncbi.nlm.nih.gov/pubmed/21589419
http://dx.doi.org/10.1107/S1600536810045253
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AT liyiqun 377trimethyl1phenyl5678tetrahydrospiroindoline341h4hpyrazolo34bchromene25dione

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