(R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate

The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(−)·C(3)H(6)O, was synthesized by N-alkyl­ation of α-amino-(2-chloro­phen­yl)acetate with 2-thienylethyl p-toluene­sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H...

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Detalles Bibliográficos
Autores principales: Liang, Yan-Shu, Mu, Shuai, Liu, Ying, Liu, Deng-Ke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011721/
https://www.ncbi.nlm.nih.gov/pubmed/21589421
http://dx.doi.org/10.1107/S160053681004523X
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author Liang, Yan-Shu
Mu, Shuai
Liu, Ying
Liu, Deng-Ke
author_facet Liang, Yan-Shu
Mu, Shuai
Liu, Ying
Liu, Deng-Ke
author_sort Liang, Yan-Shu
collection PubMed
description The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(−)·C(3)H(6)O, was synthesized by N-alkyl­ation of α-amino-(2-chloro­phen­yl)acetate with 2-thienylethyl p-toluene­sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H⋯O hydrogen bonds. The thio­phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4).
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spelling pubmed-30117212010-12-30 (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate Liang, Yan-Shu Mu, Shuai Liu, Ying Liu, Deng-Ke Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(−)·C(3)H(6)O, was synthesized by N-alkyl­ation of α-amino-(2-chloro­phen­yl)acetate with 2-thienylethyl p-toluene­sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H⋯O hydrogen bonds. The thio­phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4). International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011721/ /pubmed/21589421 http://dx.doi.org/10.1107/S160053681004523X Text en © Liang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liang, Yan-Shu
Mu, Shuai
Liu, Ying
Liu, Deng-Ke
(R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title_full (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title_fullStr (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title_full_unstemmed (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title_short (R)-[1-(2-Chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
title_sort (r)-[1-(2-chloro­phen­yl)-2-meth­oxy-2-oxoeth­yl][2-(thio­phen-2-yl)eth­yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011721/
https://www.ncbi.nlm.nih.gov/pubmed/21589421
http://dx.doi.org/10.1107/S160053681004523X
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AT mushuai r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate
AT liuying r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate
AT liudengke r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate

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