(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)copper(II) bis­[O,O′-(o-phenyl­ene)dithio­phosphate]

In the title compound, [Cu(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Cu(II) cation lies on an inversion center and is chelated by the macrocyclic tetra­amine ligand in a slightly distorted CuN(4) square-planar geometry. The axial positions are occupied by two O,O′-(o-phenyl­ene)dithio­phosphate an...

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Detalles Bibliográficos
Autores principales: Feng, Jian-Shen, Zou, Li-Ke, Xie, Bin, Xiang, Yang-Guang, Lai, Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011723/
https://www.ncbi.nlm.nih.gov/pubmed/21589276
http://dx.doi.org/10.1107/S1600536810046684
Descripción
Sumario:In the title compound, [Cu(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Cu(II) cation lies on an inversion center and is chelated by the macrocyclic tetra­amine ligand in a slightly distorted CuN(4) square-planar geometry. The axial positions are occupied by two O,O′-(o-phenyl­ene)dithio­phosphate anions with long Cu⋯S distances of 3.0940 (7) Å. Inter­molecular N—H⋯S and C—H⋯O hydrogen bonding is present between the anions and the cation and helps to stabilize the crystal structure.

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