cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate

In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, and one P a...

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Detalles Bibliográficos
Autores principales: Xu, Hui-Jun, Li, Yu, Du, Qing-Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011727/
https://www.ncbi.nlm.nih.gov/pubmed/21589336
http://dx.doi.org/10.1107/S1600536810047033
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author Xu, Hui-Jun
Li, Yu
Du, Qing-Yang
author_facet Xu, Hui-Jun
Li, Yu
Du, Qing-Yang
author_sort Xu, Hui-Jun
collection PubMed
description In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, and one P atom from a PPh(3) ligand. The two Cl atoms adopt a cis arrangement with the PPh(3) ligand trans to one Cl atom. The N,O,N′-tridentate ligand occupies a mer position in the coordination sphere.
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spelling pubmed-30117272010-12-30 cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate Xu, Hui-Jun Li, Yu Du, Qing-Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, and one P atom from a PPh(3) ligand. The two Cl atoms adopt a cis arrangement with the PPh(3) ligand trans to one Cl atom. The N,O,N′-tridentate ligand occupies a mer position in the coordination sphere. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011727/ /pubmed/21589336 http://dx.doi.org/10.1107/S1600536810047033 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Hui-Jun
Li, Yu
Du, Qing-Yang
cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_full cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_fullStr cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_full_unstemmed cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_short cis-Dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_sort cis-dichlorido[2-methyl-8-(pyridin-2-ylmeth­oxy)quinoline-κ(3) n,o,n′](triphenylphosphane-κp)ruthenium(ii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011727/
https://www.ncbi.nlm.nih.gov/pubmed/21589336
http://dx.doi.org/10.1107/S1600536810047033
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AT liyu cisdichlorido2methyl8pyridin2ylmethoxyquinolinek3nontriphenylphosphanekprutheniumiimethanolmonosolvate
AT duqingyang cisdichlorido2methyl8pyridin2ylmethoxyquinolinek3nontriphenylphosphanekprutheniumiimethanolmonosolvate

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