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Phenylhydrazinium (6-carboxypyridine-2-carboxylato)(pyridine-2,6-dicarboxylato)cobaltate(II)–pyridine-2,6-dicarboxylic acid–water (1/1/3)
The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carboxypyridine-2-carboxylato)(pyridine-2,6-dicarboxylato)cobaltate(II) anion, one phenylhydrazinium cation, one pyridine-2,6-dicarboxylic acid molecule and three...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011730/ https://www.ncbi.nlm.nih.gov/pubmed/21589313 http://dx.doi.org/10.1107/S1600536810048191 |
Sumario: | The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carboxypyridine-2-carboxylato)(pyridine-2,6-dicarboxylato)cobaltate(II) anion, one phenylhydrazinium cation, one pyridine-2,6-dicarboxylic acid molecule and three uncoordinated water molecules, part of which are disordered. The Co(II) ion is coordinated by a pyridine-2,6-dicarboxylate ion and a 6-carboxypyridine-2-carboxylate ligand almost perpendicular to each other [the angle between the least-squares planes is 87.38 (4)°] and is surrounded by two O atoms and two N atoms in the equatorial plane and two O atoms in axial positions, resulting in a distorted octahedral coordination geometry. There is an extensive three-dimensional network of O—H⋯O and N—H⋯O hydrogen bonds, which link the components. |
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