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Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)

The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II) anion, one phenyl­hydrazinium cation, one pyridine-2,6-dicarb­oxy­lic acid mol­ecule and three...

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Detalles Bibliográficos
Autores principales: Yuste, Consuelo, Ramos Silva, Manuela, Ghadermazi, Mohammad, Feizi, Fariba, Motieiyan, Elham
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011730/
https://www.ncbi.nlm.nih.gov/pubmed/21589313
http://dx.doi.org/10.1107/S1600536810048191
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author Yuste, Consuelo
Ramos Silva, Manuela
Ghadermazi, Mohammad
Feizi, Fariba
Motieiyan, Elham
author_facet Yuste, Consuelo
Ramos Silva, Manuela
Ghadermazi, Mohammad
Feizi, Fariba
Motieiyan, Elham
author_sort Yuste, Consuelo
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II) anion, one phenyl­hydrazinium cation, one pyridine-2,6-dicarb­oxy­lic acid mol­ecule and three uncoordin­ated water mol­ecules, part of which are disordered. The Co(II) ion is coordinated by a pyridine-2,6-dicarboxyl­ate ion and a 6-carb­oxy­pyridine-2-carboxyl­ate ligand almost perpendicular to each other [the angle between the least-squares planes is 87.38 (4)°] and is surrounded by two O atoms and two N atoms in the equatorial plane and two O atoms in axial positions, resulting in a distorted octa­hedral coordination geometry. There is an extensive three-dimensional network of O—H⋯O and N—H⋯O hydrogen bonds, which link the components.
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spelling pubmed-30117302010-12-30 Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3) Yuste, Consuelo Ramos Silva, Manuela Ghadermazi, Mohammad Feizi, Fariba Motieiyan, Elham Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II) anion, one phenyl­hydrazinium cation, one pyridine-2,6-dicarb­oxy­lic acid mol­ecule and three uncoordin­ated water mol­ecules, part of which are disordered. The Co(II) ion is coordinated by a pyridine-2,6-dicarboxyl­ate ion and a 6-carb­oxy­pyridine-2-carboxyl­ate ligand almost perpendicular to each other [the angle between the least-squares planes is 87.38 (4)°] and is surrounded by two O atoms and two N atoms in the equatorial plane and two O atoms in axial positions, resulting in a distorted octa­hedral coordination geometry. There is an extensive three-dimensional network of O—H⋯O and N—H⋯O hydrogen bonds, which link the components. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011730/ /pubmed/21589313 http://dx.doi.org/10.1107/S1600536810048191 Text en © Yuste et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuste, Consuelo
Ramos Silva, Manuela
Ghadermazi, Mohammad
Feizi, Fariba
Motieiyan, Elham
Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title_full Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title_fullStr Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title_full_unstemmed Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title_short Phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(II)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
title_sort phenyl­hydrazinium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cobaltate(ii)–pyridine-2,6-dicarb­oxy­lic acid–water (1/1/3)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011730/
https://www.ncbi.nlm.nih.gov/pubmed/21589313
http://dx.doi.org/10.1107/S1600536810048191
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