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Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate

In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxyl­ate (1,3-BDC) ligand and three from water mol­ecules, in...

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Detalles Bibliográficos
Autor principal: Fang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011731/
https://www.ncbi.nlm.nih.gov/pubmed/21589259
http://dx.doi.org/10.1107/S1600536810045551
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author Fang, Wei
author_facet Fang, Wei
author_sort Fang, Wei
collection PubMed
description In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxyl­ate (1,3-BDC) ligand and three from water mol­ecules, in a distorted penta­gonal-bipyramidal geometry. Neighbouring units inter­act through π–π inter­actions [centroid–centroid distances = 3.380 (3) and 3.283 (4) Å]. Finally, three types of O—H⋯O hydrogen bonds exist between coordinated dissociative water mol­ecules and hybridization water mol­ecules and carboxyl­ate O atoms, resulting in a two-dimensional network parallel to (010).
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spelling pubmed-30117312010-12-30 Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate Fang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxyl­ate (1,3-BDC) ligand and three from water mol­ecules, in a distorted penta­gonal-bipyramidal geometry. Neighbouring units inter­act through π–π inter­actions [centroid–centroid distances = 3.380 (3) and 3.283 (4) Å]. Finally, three types of O—H⋯O hydrogen bonds exist between coordinated dissociative water mol­ecules and hybridization water mol­ecules and carboxyl­ate O atoms, resulting in a two-dimensional network parallel to (010). International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011731/ /pubmed/21589259 http://dx.doi.org/10.1107/S1600536810045551 Text en © Wei Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fang, Wei
Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title_full Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title_fullStr Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title_full_unstemmed Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title_short Triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(II) penta­hydrate
title_sort triaqua­(benzene-1,3-dicarboxyl­ato)(4,5-diaza­fluoren-9-one)cadmium(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011731/
https://www.ncbi.nlm.nih.gov/pubmed/21589259
http://dx.doi.org/10.1107/S1600536810045551
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