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Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate
In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxylate (1,3-BDC) ligand and three from water molecules, in...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011731/ https://www.ncbi.nlm.nih.gov/pubmed/21589259 http://dx.doi.org/10.1107/S1600536810045551 |
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author | Fang, Wei |
author_facet | Fang, Wei |
author_sort | Fang, Wei |
collection | PubMed |
description | In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxylate (1,3-BDC) ligand and three from water molecules, in a distorted pentagonal-bipyramidal geometry. Neighbouring units interact through π–π interactions [centroid–centroid distances = 3.380 (3) and 3.283 (4) Å]. Finally, three types of O—H⋯O hydrogen bonds exist between coordinated dissociative water molecules and hybridization water molecules and carboxylate O atoms, resulting in a two-dimensional network parallel to (010). |
format | Text |
id | pubmed-3011731 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117312010-12-30 Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate Fang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxylate (1,3-BDC) ligand and three from water molecules, in a distorted pentagonal-bipyramidal geometry. Neighbouring units interact through π–π interactions [centroid–centroid distances = 3.380 (3) and 3.283 (4) Å]. Finally, three types of O—H⋯O hydrogen bonds exist between coordinated dissociative water molecules and hybridization water molecules and carboxylate O atoms, resulting in a two-dimensional network parallel to (010). International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011731/ /pubmed/21589259 http://dx.doi.org/10.1107/S1600536810045551 Text en © Wei Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fang, Wei Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title | Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title_full | Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title_fullStr | Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title_full_unstemmed | Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title_short | Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate |
title_sort | triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(ii) pentahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011731/ https://www.ncbi.nlm.nih.gov/pubmed/21589259 http://dx.doi.org/10.1107/S1600536810045551 |
work_keys_str_mv | AT fangwei triaquabenzene13dicarboxylato45diazafluoren9onecadmiumiipentahydrate |