Cargando…
3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane
The title compound, C(15)H(28)O(4), was prepared by the condensation of pivalaldehyde with pentaerythritol. In the crystal, the two halves of the molecule are related by a crystallographic twofold rotation axis passing through the central spiro-C atom. The two non-planar six-membered heterocycles...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011739/ https://www.ncbi.nlm.nih.gov/pubmed/21589636 http://dx.doi.org/10.1107/S1600536810049524 |
_version_ | 1782195014760136704 |
---|---|
author | Li, Zhengyi Chen, Liang Tang, Qiuzheng Sun, Xiaoqiang |
author_facet | Li, Zhengyi Chen, Liang Tang, Qiuzheng Sun, Xiaoqiang |
author_sort | Li, Zhengyi |
collection | PubMed |
description | The title compound, C(15)H(28)O(4), was prepared by the condensation of pivalaldehyde with pentaerythritol. In the crystal, the two halves of the molecule are related by a crystallographic twofold rotation axis passing through the central spiro-C atom. The two non-planar six-membered heterocycles both adopt chair conformations with the two tert-butyl groups both located in the equatorial positions. |
format | Text |
id | pubmed-3011739 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117392010-12-30 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane Li, Zhengyi Chen, Liang Tang, Qiuzheng Sun, Xiaoqiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(28)O(4), was prepared by the condensation of pivalaldehyde with pentaerythritol. In the crystal, the two halves of the molecule are related by a crystallographic twofold rotation axis passing through the central spiro-C atom. The two non-planar six-membered heterocycles both adopt chair conformations with the two tert-butyl groups both located in the equatorial positions. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011739/ /pubmed/21589636 http://dx.doi.org/10.1107/S1600536810049524 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Zhengyi Chen, Liang Tang, Qiuzheng Sun, Xiaoqiang 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title | 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title_full | 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title_fullStr | 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title_full_unstemmed | 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title_short | 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
title_sort | 3,9-di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011739/ https://www.ncbi.nlm.nih.gov/pubmed/21589636 http://dx.doi.org/10.1107/S1600536810049524 |
work_keys_str_mv | AT lizhengyi 39ditertbutyl24810tetraoxaspiro55undecane AT chenliang 39ditertbutyl24810tetraoxaspiro55undecane AT tangqiuzheng 39ditertbutyl24810tetraoxaspiro55undecane AT sunxiaoqiang 39ditertbutyl24810tetraoxaspiro55undecane |