(2,2′-Bipyridine-κ(2) N,N′)chlorido(1,4,7-trithia­cyclo­nonane-κ(3) S,S′,S′′)ruthenium(II) nitrate monohydrate

In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri­thia­cyclo­nonane and bpy is 2,2′-bipyridine), the Ru(II) cation has a slightly distorted octa­hedral environment composed of three facially coordinated S atoms from...

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Detalles Bibliográficos
Autores principales: Fernandes, José A., Almeida Paz, Filipe A., Mota, Maria João P., Braga, Susana S., Santos, Teresa M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011741/
https://www.ncbi.nlm.nih.gov/pubmed/21589261
http://dx.doi.org/10.1107/S1600536810046556
Descripción
Sumario:In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri­thia­cyclo­nonane and bpy is 2,2′-bipyridine), the Ru(II) cation has a slightly distorted octa­hedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol­ecule of crystallization are engaged in O—H⋯O hydrogen-bonding inter­actions, leading to a supra­molecular chain running parallel to the c axis.

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