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(2,2′-Bipyridine-κ(2) N,N′)chlorido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) nitrate monohydrate
In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), the Ru(II) cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011741/ https://www.ncbi.nlm.nih.gov/pubmed/21589261 http://dx.doi.org/10.1107/S1600536810046556 |
| _version_ | 1782195015224655872 |
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| author | Fernandes, José A. Almeida Paz, Filipe A. Mota, Maria João P. Braga, Susana S. Santos, Teresa M. |
| author_facet | Fernandes, José A. Almeida Paz, Filipe A. Mota, Maria João P. Braga, Susana S. Santos, Teresa M. |
| author_sort | Fernandes, José A. |
| collection | PubMed |
| description | In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), the Ru(II) cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water molecule of crystallization are engaged in O—H⋯O hydrogen-bonding interactions, leading to a supramolecular chain running parallel to the c axis. |
| format | Text |
| id | pubmed-3011741 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30117412010-12-30 (2,2′-Bipyridine-κ(2) N,N′)chlorido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) nitrate monohydrate Fernandes, José A. Almeida Paz, Filipe A. Mota, Maria João P. Braga, Susana S. Santos, Teresa M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), the Ru(II) cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water molecule of crystallization are engaged in O—H⋯O hydrogen-bonding interactions, leading to a supramolecular chain running parallel to the c axis. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011741/ /pubmed/21589261 http://dx.doi.org/10.1107/S1600536810046556 Text en © Fernandes et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fernandes, José A. Almeida Paz, Filipe A. Mota, Maria João P. Braga, Susana S. Santos, Teresa M. (2,2′-Bipyridine-κ(2) N,N′)chlorido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) nitrate monohydrate |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)chlorido(1,4,7-trithiacyclononane-κ(3)
s,s′,s′′)ruthenium(ii) nitrate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011741/ https://www.ncbi.nlm.nih.gov/pubmed/21589261 http://dx.doi.org/10.1107/S1600536810046556 |
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