catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]

In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa­hedral geometry. The bridging ligan...

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Detalles Bibliográficos
Autores principales: Huang, Ping-Yun, Wang, Jin-Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011745/
https://www.ncbi.nlm.nih.gov/pubmed/21589310
http://dx.doi.org/10.1107/S160053681004715X
Descripción
Sumario:In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa­hedral geometry. The bridging ligand, which is completed by crystallographic twofold symmetry, links the Co(II) atoms into [10[Image: see text]] chains. Within the ligand, the dihedral angle between the benzene and benzimidazole rings is 48.31 (8)°.

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