catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]

In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa­hedral geometry. The bridging ligan...

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Detalles Bibliográficos
Autores principales: Huang, Ping-Yun, Wang, Jin-Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011745/
https://www.ncbi.nlm.nih.gov/pubmed/21589310
http://dx.doi.org/10.1107/S160053681004715X
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author Huang, Ping-Yun
Wang, Jin-Guo
author_facet Huang, Ping-Yun
Wang, Jin-Guo
author_sort Huang, Ping-Yun
collection PubMed
description In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa­hedral geometry. The bridging ligand, which is completed by crystallographic twofold symmetry, links the Co(II) atoms into [10[Image: see text]] chains. Within the ligand, the dihedral angle between the benzene and benzimidazole rings is 48.31 (8)°.
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spelling pubmed-30117452010-12-30 catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)] Huang, Ping-Yun Wang, Jin-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa­hedral geometry. The bridging ligand, which is completed by crystallographic twofold symmetry, links the Co(II) atoms into [10[Image: see text]] chains. Within the ligand, the dihedral angle between the benzene and benzimidazole rings is 48.31 (8)°. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011745/ /pubmed/21589310 http://dx.doi.org/10.1107/S160053681004715X Text en © Huang and Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Ping-Yun
Wang, Jin-Guo
catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title_full catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title_short catena-Poly[[bis­(acetato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) N (3):N (3′)]
title_sort catena-poly[[bis­(acetato-κ(2) o,o′)cobalt(ii)]-μ-4,4′-bis­(benzimidazol-1-yl)biphenyl-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011745/
https://www.ncbi.nlm.nih.gov/pubmed/21589310
http://dx.doi.org/10.1107/S160053681004715X
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AT wangjinguo catenapolybisacetatok2oocobaltiim44bisbenzimidazol1ylbiphenylk2n3n3

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