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1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three methoxy groups of 2,4,5-trimethoxyphenyl are essentially coplanar with the benzene plane,...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011747/ https://www.ncbi.nlm.nih.gov/pubmed/21589405 http://dx.doi.org/10.1107/S1600536810043254 |
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author | Mueangkeaw, Charoensak Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun |
author_facet | Mueangkeaw, Charoensak Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun |
author_sort | Mueangkeaw, Charoensak |
collection | PubMed |
description | In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three methoxy groups of 2,4,5-trimethoxyphenyl are essentially coplanar with the benzene plane, with C—O—C—C torsion angles of 1.0 (3), −1.9 (3) and 3.6 (3)°. A weak intramolecular C—H⋯O interaction generates an S(6) ring motif. In the crystal, the cations are stacked in columns in an antiparallel manner along the a axis through π–π interactions, with a centroid–centroid distance of 3.7714 (16) Å. The iodide anion is situated between the columns and linked to the cation by a weak C—H⋯I interaction. |
format | Text |
id | pubmed-3011747 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117472010-12-30 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide Mueangkeaw, Charoensak Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three methoxy groups of 2,4,5-trimethoxyphenyl are essentially coplanar with the benzene plane, with C—O—C—C torsion angles of 1.0 (3), −1.9 (3) and 3.6 (3)°. A weak intramolecular C—H⋯O interaction generates an S(6) ring motif. In the crystal, the cations are stacked in columns in an antiparallel manner along the a axis through π–π interactions, with a centroid–centroid distance of 3.7714 (16) Å. The iodide anion is situated between the columns and linked to the cation by a weak C—H⋯I interaction. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011747/ /pubmed/21589405 http://dx.doi.org/10.1107/S1600536810043254 Text en © Mueangkeaw et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mueangkeaw, Charoensak Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide |
title | 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
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title_full | 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
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title_fullStr | 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
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title_full_unstemmed | 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
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title_short | 1-Methyl-2-[(E)-2,4,5-trimethoxystyryl]pyridinium iodide
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title_sort | 1-methyl-2-[(e)-2,4,5-trimethoxystyryl]pyridinium iodide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011747/ https://www.ncbi.nlm.nih.gov/pubmed/21589405 http://dx.doi.org/10.1107/S1600536810043254 |
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