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1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide

In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three meth­oxy groups of 2,4,5-trimeth­oxy­phenyl are essentially coplanar with the benzene plane,...

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Autores principales: Mueangkeaw, Charoensak, Chantrapromma, Suchada, Ruanwas, Pumsak, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011747/
https://www.ncbi.nlm.nih.gov/pubmed/21589405
http://dx.doi.org/10.1107/S1600536810043254
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author Mueangkeaw, Charoensak
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
author_facet Mueangkeaw, Charoensak
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
author_sort Mueangkeaw, Charoensak
collection PubMed
description In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three meth­oxy groups of 2,4,5-trimeth­oxy­phenyl are essentially coplanar with the benzene plane, with C—O—C—C torsion angles of 1.0 (3), −1.9 (3) and 3.6 (3)°. A weak intra­molecular C—H⋯O inter­action generates an S(6) ring motif. In the crystal, the cations are stacked in columns in an anti­parallel manner along the a axis through π–π inter­actions, with a centroid–centroid distance of 3.7714 (16) Å. The iodide anion is situated between the columns and linked to the cation by a weak C—H⋯I inter­action.
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spelling pubmed-30117472010-12-30 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide Mueangkeaw, Charoensak Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(20)NO(3) (+)·I(−), the cation exists in the E configuration. The pyridinium and benzene rings are close to coplanar, with a dihedral angle of 7.43 (12)° between them. The three meth­oxy groups of 2,4,5-trimeth­oxy­phenyl are essentially coplanar with the benzene plane, with C—O—C—C torsion angles of 1.0 (3), −1.9 (3) and 3.6 (3)°. A weak intra­molecular C—H⋯O inter­action generates an S(6) ring motif. In the crystal, the cations are stacked in columns in an anti­parallel manner along the a axis through π–π inter­actions, with a centroid–centroid distance of 3.7714 (16) Å. The iodide anion is situated between the columns and linked to the cation by a weak C—H⋯I inter­action. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011747/ /pubmed/21589405 http://dx.doi.org/10.1107/S1600536810043254 Text en © Mueangkeaw et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mueangkeaw, Charoensak
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title_full 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title_fullStr 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title_full_unstemmed 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title_short 1-Methyl-2-[(E)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
title_sort 1-methyl-2-[(e)-2,4,5-trimeth­oxy­styr­yl]­pyridinium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011747/
https://www.ncbi.nlm.nih.gov/pubmed/21589405
http://dx.doi.org/10.1107/S1600536810043254
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