14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine

The title compound, C(28)H(19)NO(2), was synthesized by the reaction of 1,3-benzodioxole-5-carbaldehyde with naphthalen-2-amine catalyzed by thio­salicylic acid in acetic acid. The central dihydropyridine ring adopts a boat conformation. The two planar (r.m.s. deviations = 0.0158 and 0.0552 Å) bicyc...

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Detalles Bibliográficos
Autores principales: Jia, Runhong, Peng, Juhua, Tu, ShuJiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011748/
https://www.ncbi.nlm.nih.gov/pubmed/21589382
http://dx.doi.org/10.1107/S1600536810044302
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author Jia, Runhong
Peng, Juhua
Tu, ShuJiang
author_facet Jia, Runhong
Peng, Juhua
Tu, ShuJiang
author_sort Jia, Runhong
collection PubMed
description The title compound, C(28)H(19)NO(2), was synthesized by the reaction of 1,3-benzodioxole-5-carbaldehyde with naphthalen-2-amine catalyzed by thio­salicylic acid in acetic acid. The central dihydropyridine ring adopts a boat conformation. The two planar (r.m.s. deviations = 0.0158 and 0.0552 Å) bicyclic parts make a dihedral angle of 16.16 (5)° with respect to each other. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-30117482010-12-30 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine Jia, Runhong Peng, Juhua Tu, ShuJiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(19)NO(2), was synthesized by the reaction of 1,3-benzodioxole-5-carbaldehyde with naphthalen-2-amine catalyzed by thio­salicylic acid in acetic acid. The central dihydropyridine ring adopts a boat conformation. The two planar (r.m.s. deviations = 0.0158 and 0.0552 Å) bicyclic parts make a dihedral angle of 16.16 (5)° with respect to each other. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011748/ /pubmed/21589382 http://dx.doi.org/10.1107/S1600536810044302 Text en © Jia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jia, Runhong
Peng, Juhua
Tu, ShuJiang
14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title_full 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title_fullStr 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title_full_unstemmed 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title_short 14-(1,3-Benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
title_sort 14-(1,3-benzodioxol-5-yl)-7,14-dihydro­dibenzo[a,j]acridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011748/
https://www.ncbi.nlm.nih.gov/pubmed/21589382
http://dx.doi.org/10.1107/S1600536810044302
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AT tushujiang 1413benzodioxol5yl714dihydrodibenzoajacridine

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