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Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the...

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Autores principales: Salam, Md. Abdus, Affan, Md. Abu, Ahmad, Fasihuddin B., Tahir, M. Ibrahim Mohamed, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011751/
https://www.ncbi.nlm.nih.gov/pubmed/21589211
http://dx.doi.org/10.1107/S1600536810044247
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author Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Tahir, M. Ibrahim Mohamed
Tiekink, Edward R. T.
author_facet Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Tahir, M. Ibrahim Mohamed
Tiekink, Edward R. T.
author_sort Salam, Md. Abdus
collection PubMed
description The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)°]. With the exception of the cyclo­hexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 Å). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)°] to the planar portion of the Schiff base allows for the formation of significant intra­molecular C—H⋯Cl inter­actions which preclude the Cl atoms from participating in N—H⋯Cl hydrogen bonds. Instead, C—H⋯π contacts, involving methyl­ene H and the Sn-bound phenyl group, lead to the formation of supra­molecular chains that pack in the bc plane. Connections between these layers are of the type C—H⋯Cl.
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spelling pubmed-30117512010-12-30 Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV) Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Tahir, M. Ibrahim Mohamed Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)°]. With the exception of the cyclo­hexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 Å). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)°] to the planar portion of the Schiff base allows for the formation of significant intra­molecular C—H⋯Cl inter­actions which preclude the Cl atoms from participating in N—H⋯Cl hydrogen bonds. Instead, C—H⋯π contacts, involving methyl­ene H and the Sn-bound phenyl group, lead to the formation of supra­molecular chains that pack in the bc plane. Connections between these layers are of the type C—H⋯Cl. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011751/ /pubmed/21589211 http://dx.doi.org/10.1107/S1600536810044247 Text en © Salam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Tahir, M. Ibrahim Mohamed
Tiekink, Edward R. T.
Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title_full Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title_fullStr Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title_full_unstemmed Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title_short Dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}phenyl­tin(IV)
title_sort dichlorido{4-cyclo­hexyl-1-[1-(2-pyridyl-κn)ethyl­idene]thio­semicarbazidato-κ(2) n (1),s}phenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011751/
https://www.ncbi.nlm.nih.gov/pubmed/21589211
http://dx.doi.org/10.1107/S1600536810044247
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