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Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}phenyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octahedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011751/ https://www.ncbi.nlm.nih.gov/pubmed/21589211 http://dx.doi.org/10.1107/S1600536810044247 |
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author | Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Tahir, M. Ibrahim Mohamed Tiekink, Edward R. T. |
author_facet | Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Tahir, M. Ibrahim Mohamed Tiekink, Edward R. T. |
author_sort | Salam, Md. Abdus |
collection | PubMed |
description | The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octahedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)°]. With the exception of the cyclohexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 Å). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)°] to the planar portion of the Schiff base allows for the formation of significant intramolecular C—H⋯Cl interactions which preclude the Cl atoms from participating in N—H⋯Cl hydrogen bonds. Instead, C—H⋯π contacts, involving methylene H and the Sn-bound phenyl group, lead to the formation of supramolecular chains that pack in the bc plane. Connections between these layers are of the type C—H⋯Cl. |
format | Text |
id | pubmed-3011751 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117512010-12-30 Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}phenyltin(IV) Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Tahir, M. Ibrahim Mohamed Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(C(14)H(19)N(4)S)Cl(2)], exists within a distorted octahedral geometry defined by the N,N′,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)°]. With the exception of the cyclohexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 Å). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)°] to the planar portion of the Schiff base allows for the formation of significant intramolecular C—H⋯Cl interactions which preclude the Cl atoms from participating in N—H⋯Cl hydrogen bonds. Instead, C—H⋯π contacts, involving methylene H and the Sn-bound phenyl group, lead to the formation of supramolecular chains that pack in the bc plane. Connections between these layers are of the type C—H⋯Cl. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011751/ /pubmed/21589211 http://dx.doi.org/10.1107/S1600536810044247 Text en © Salam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Tahir, M. Ibrahim Mohamed Tiekink, Edward R. T. Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}phenyltin(IV) |
title | Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}phenyltin(IV) |
title_full | Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}phenyltin(IV) |
title_fullStr | Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}phenyltin(IV) |
title_full_unstemmed | Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}phenyltin(IV) |
title_short | Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}phenyltin(IV) |
title_sort | dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κn)ethylidene]thiosemicarbazidato-κ(2)
n
(1),s}phenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011751/ https://www.ncbi.nlm.nih.gov/pubmed/21589211 http://dx.doi.org/10.1107/S1600536810044247 |
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