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(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate]
The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphenyl[14]dien)](2+) dication (meso-diphenyl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and two O,O′-bis(4-methylphenyl) dithiophosp...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011755/ https://www.ncbi.nlm.nih.gov/pubmed/21589325 http://dx.doi.org/10.1107/S160053681004849X |
Sumario: | The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphenyl[14]dien)](2+) dication (meso-diphenyl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and two O,O′-bis(4-methylphenyl) dithiophosphate anions. The Ni(II) ion lies on an inversion center and is chelated by a tetraamine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni(II) ion, with Ni⋯S distances of 3.1869 (8) Å. In the crystal, bifurcated intermolecular N—H⋯S(S) hydrogen bonds connect cations and pairs of anions into three-component clusters. Weak intermolecular C—H⋯S hydrogen bonds link these clusters into chains along [100]. |
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