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(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene)nickel(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]

The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphen­yl[14]dien)](2+) dication (meso-diphen­yl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene) and two O,O′-bis­(4-methyl­phen­yl) dithio­phosp...

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Detalles Bibliográficos
Autores principales: Zou, Li-Ke, Xie, Bin, Feng, Jian-Shen, Lai, Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011755/
https://www.ncbi.nlm.nih.gov/pubmed/21589325
http://dx.doi.org/10.1107/S160053681004849X
Descripción
Sumario:The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphen­yl[14]dien)](2+) dication (meso-diphen­yl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene) and two O,O′-bis­(4-methyl­phen­yl) dithio­phosphate anions. The Ni(II) ion lies on an inversion center and is chelated by a tetra­amine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni(II) ion, with Ni⋯S distances of 3.1869 (8) Å. In the crystal, bifurcated inter­molecular N—H⋯S(S) hydrogen bonds connect cations and pairs of anions into three-component clusters. Weak inter­molecular C—H⋯S hydrogen bonds link these clusters into chains along [100].