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(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate]
The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphenyl[14]dien)](2+) dication (meso-diphenyl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and two O,O′-bis(4-methylphenyl) dithiophosp...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011755/ https://www.ncbi.nlm.nih.gov/pubmed/21589325 http://dx.doi.org/10.1107/S160053681004849X |
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author | Zou, Li-Ke Xie, Bin Feng, Jian-Shen Lai, Chuan |
author_facet | Zou, Li-Ke Xie, Bin Feng, Jian-Shen Lai, Chuan |
author_sort | Zou, Li-Ke |
collection | PubMed |
description | The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphenyl[14]dien)](2+) dication (meso-diphenyl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and two O,O′-bis(4-methylphenyl) dithiophosphate anions. The Ni(II) ion lies on an inversion center and is chelated by a tetraamine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni(II) ion, with Ni⋯S distances of 3.1869 (8) Å. In the crystal, bifurcated intermolecular N—H⋯S(S) hydrogen bonds connect cations and pairs of anions into three-component clusters. Weak intermolecular C—H⋯S hydrogen bonds link these clusters into chains along [100]. |
format | Text |
id | pubmed-3011755 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30117552010-12-30 (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] Zou, Li-Ke Xie, Bin Feng, Jian-Shen Lai, Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), comprises a centrosymmetric [Ni(meso-diphenyl[14]dien)](2+) dication (meso-diphenyl[14]dien is C-meso-N-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and two O,O′-bis(4-methylphenyl) dithiophosphate anions. The Ni(II) ion lies on an inversion center and is chelated by a tetraamine macrocycle ligand in a slightly distorted NiN(4) square-planar geometry. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni(II) ion, with Ni⋯S distances of 3.1869 (8) Å. In the crystal, bifurcated intermolecular N—H⋯S(S) hydrogen bonds connect cations and pairs of anions into three-component clusters. Weak intermolecular C—H⋯S hydrogen bonds link these clusters into chains along [100]. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011755/ /pubmed/21589325 http://dx.doi.org/10.1107/S160053681004849X Text en © Zou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zou, Li-Ke Xie, Bin Feng, Jian-Shen Lai, Chuan (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title | (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title_full | (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title_fullStr | (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title_full_unstemmed | (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title_short | (C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate] |
title_sort | (c-meso-n-meso-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(ii) bis[o,o′-bis(4-methylphenyl) dithiophosphate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011755/ https://www.ncbi.nlm.nih.gov/pubmed/21589325 http://dx.doi.org/10.1107/S160053681004849X |
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