Bis(2-acetylpyridine-κ(2) N,O)silver(I) tetra­fluoridoborate: a complex with silver in a seesaw coordination geometry

The reaction of 2-acetylpyridine with silver(I) tetra­fluorido­borate leads to the discrete title complex, [Ag(C(7)H(7)NO)(2)]BF(4), in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is N,O-bidentate, albeit with stronger bonding to the N atoms [Ag—N =...

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Detalles Bibliográficos
Autores principales: O’Donnell, Michael A., Steel, Peter J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011758/
https://www.ncbi.nlm.nih.gov/pubmed/21589304
http://dx.doi.org/10.1107/S1600536810048014
Descripción
Sumario:The reaction of 2-acetylpyridine with silver(I) tetra­fluorido­borate leads to the discrete title complex, [Ag(C(7)H(7)NO)(2)]BF(4), in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is N,O-bidentate, albeit with stronger bonding to the N atoms [Ag—N = 2.2018 (15) and 2.2088 (14) Å; Ag—O = 2.5380 (13) and 2.5454 (13) Å]. The four-coordinate Ag atom has a seesaw coordination geometry with a τ(4) index of 0.51. The tetra­fluoridoborate anion is disordered over two orientations with 0.568 (10):0.432 (10) occupancies.

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