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Bis(2-acetylpyridine-κ(2) N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry
The reaction of 2-acetylpyridine with silver(I) tetrafluoridoborate leads to the discrete title complex, [Ag(C(7)H(7)NO)(2)]BF(4), in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is N,O-bidentate, albeit with stronger bonding to the N atoms [Ag—N =...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011758/ https://www.ncbi.nlm.nih.gov/pubmed/21589304 http://dx.doi.org/10.1107/S1600536810048014 |
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| author | O’Donnell, Michael A. Steel, Peter J. |
| author_facet | O’Donnell, Michael A. Steel, Peter J. |
| author_sort | O’Donnell, Michael A. |
| collection | PubMed |
| description | The reaction of 2-acetylpyridine with silver(I) tetrafluoridoborate leads to the discrete title complex, [Ag(C(7)H(7)NO)(2)]BF(4), in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is N,O-bidentate, albeit with stronger bonding to the N atoms [Ag—N = 2.2018 (15) and 2.2088 (14) Å; Ag—O = 2.5380 (13) and 2.5454 (13) Å]. The four-coordinate Ag atom has a seesaw coordination geometry with a τ(4) index of 0.51. The tetrafluoridoborate anion is disordered over two orientations with 0.568 (10):0.432 (10) occupancies. |
| format | Text |
| id | pubmed-3011758 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30117582010-12-30 Bis(2-acetylpyridine-κ(2) N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry O’Donnell, Michael A. Steel, Peter J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 2-acetylpyridine with silver(I) tetrafluoridoborate leads to the discrete title complex, [Ag(C(7)H(7)NO)(2)]BF(4), in the cation of which the Ag atom is coordinated by two 2-acetylpyridine ligands, each of which is N,O-bidentate, albeit with stronger bonding to the N atoms [Ag—N = 2.2018 (15) and 2.2088 (14) Å; Ag—O = 2.5380 (13) and 2.5454 (13) Å]. The four-coordinate Ag atom has a seesaw coordination geometry with a τ(4) index of 0.51. The tetrafluoridoborate anion is disordered over two orientations with 0.568 (10):0.432 (10) occupancies. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011758/ /pubmed/21589304 http://dx.doi.org/10.1107/S1600536810048014 Text en © O'Donnell and Steel 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers O’Donnell, Michael A. Steel, Peter J. Bis(2-acetylpyridine-κ(2) N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title | Bis(2-acetylpyridine-κ(2)
N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title_full | Bis(2-acetylpyridine-κ(2)
N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title_fullStr | Bis(2-acetylpyridine-κ(2)
N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title_full_unstemmed | Bis(2-acetylpyridine-κ(2)
N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title_short | Bis(2-acetylpyridine-κ(2)
N,O)silver(I) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| title_sort | bis(2-acetylpyridine-κ(2)
n,o)silver(i) tetrafluoridoborate: a complex with silver in a seesaw coordination geometry |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011758/ https://www.ncbi.nlm.nih.gov/pubmed/21589304 http://dx.doi.org/10.1107/S1600536810048014 |
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